0000000000190566
AUTHOR
F. Sanz-ruiz
Bis(diethylenetriamine-κ3N)nickel(II) 5-amino-1,3,4-thiadiazole-2-sulfonamidate chloride monohydrate
In the X-ray crystal structure of the title complex, [Ni(C(4)H(13)N(3))(2)](C(2)H(3)N(4)O(2)S(2))Cl.H(2)O, the coordination polyhedron is composed of non-centrosymmetric [Ni(diethylenetriamine)(2)](2+) cations in which the triamine ligands coordinate to the metal centre as tridentate ligands in a facial position. The Ni(II) ions are linked to six N atoms in an octahedral arrangement, slightly compressed in one extreme. The sulfonamide behaves as a counter-ion instead of as a ligand. Important information about the deprotonated sulfonamide group conformation has been obtained.
CCDC 140608: Experimental Crystal Structure Determination
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CCDC 140609: Experimental Crystal Structure Determination
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CCDC 178883: Experimental Crystal Structure Determination
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CCDC 140610: Experimental Crystal Structure Determination
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CCDC 165343: Experimental Crystal Structure Determination
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CCDC 140611: Experimental Crystal Structure Determination
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CCDC 174791: Experimental Crystal Structure Determination
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CCDC 611439: Experimental Crystal Structure Determination
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CCDC 199762: Experimental Crystal Structure Determination
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