Author: M.-p. Coquard

0000000000206433

AUTHOR

M.-p. Coquard

showing 1 related works from this author

Dynamical Stark Effect in the nu(2)/nu(4) Vibrational Polyad of SiH(4): Theory and Observation.

2000

We report a theoretical and experimental investigation of the dynamical Stark effect in a tetrahedral molecule, silane (SiH(4)). We use a tetrahedral formalism and Floquet theory to calculate the absorption spectra for the molecule dressed by an intense nonresonant pulsed laser. Experimentally, the dynamical Stark effect is observed for transitions of the nu(2)/nu(4) vibrational polyad of SiH(4) by means of nanosecond diode laser absorption spectroscopy and a Nd:YAG laser excitation. Copyright 2000 Academic Press.

Floquet theoryAbsorption spectroscopyTRANSITIONS01 natural sciences010305 fluids & plasmaslaw.inventionsymbols.namesakeMOLECULESOpticslawDIPOLE-MOMENT0103 physical sciences3-LEVEL SYSTEMMoleculeSPECTRAPhysical and Theoretical Chemistry010306 general physicsSpectroscopyPhysicsbusiness.industryTetrahedral molecular geometryNanosecondRESONANCELaserAtomic and Molecular Physics and Optics3. Good healthStark effectDYADsymbolsAtomic physicsbusinessExcitationJournal of molecular spectroscopy

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