0000000000212682
AUTHOR
C. Sunseri
showing 9 related works from this author
Electrodeposition and characterization of Mo oxide nanostructures
2015
Template electrodeposition has been used to grow uniform arrays of molybdenum oxide nanostructures in polycarbonate membrane. Several parameters have been investigated, like electrodeposition, time and solution pH. These parameters do not influence the nature of the deposit that always consists of mixed valence molybdenum oxides, whereas the nanostructure morphology changes with pH. In particular, at low pH (2.7), nanotubes are formed, whilst arrays of nanowires are obtained above pH 5.5. This change of morphology is likely due to H2 bubbles evolution during the electrochemical deposition, particularly occurring at low pH. It was found that fast removal of H2 bubbles through vigorous stirri…
Nanowire ordered Arrays for electrochemical sensing of H2O2
2016
In this work, we present the performance of nanostructured array of Cu for electrochemical sensors of hydrogen peroxide. Nanostructured sensors are obtained by template synthesis in commercial polycarbonate membranes. Arrays of Cu nanowires were fabricated through a displacement deposition reaction that permits to obtain nanostructures directly and without the use of an external power supply. To test the performance of nanostructured sensors, electrochemical experiments were carried out in an aqueous solution with different amounts of hydrogen peroxide. In order to obtain sensors with stable performance, we found that it is essential to increase wettability of the nanostructures through add…
Nickel-Indium Sulphide Core-Shell Nanostructures Obtained by Spray-ILGAR Deposition
2013
Ni nanowires (NWs) of different lengths were fabricated by pulsed potentiostatic deposition within pores of polycarbonate membranes. After template dissolution, substrates underwent sequential Spray-ILGAR (R) depositions of thin indium sulphide films. The effect of deposition temperature was also investigated. For low number of deposition cycles, results showed complete and uniform covering of metal over the entire length of NWs, with formation of Ni - In2S3 core-shell structures. However, with increasing number of deposition cycles films became uneven and crusty, especially at higher temperatures, owing to the simultaneous formation of nickel sulfide. This drawback was almost eliminated do…
Nanostructured anode material for Li-ion battery obtained by galvanic process
2016
This work focused on the synthesis and characterization of nanostructured lead hydroxide chloride (PbOHCl) that is an innovative anode material for lithium-ion batteries (LIBs). In particular, we have obtained nanostructures of mixed PbOHCl and lead metal, directly into the pores of a commercially available alumina membrane, acting as template. The process was based on galvanic displacement reaction that was carried out in a two-compartment electrochemical cell without the use of an external power supply. This simple and cheap procedure gives regular array of Pb/PbOHCl composite nanowires. To obtain nanostructured electrodes is a significant result because, it’s well known that nanostructur…
Fabrication and characterization of Metal and Metal Oxide Nanostructures Grown by metal displacement deposition into anodic alumina membranes
2011
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Fabrication and characterization of nanostructured Ni and Pd electrodes for hydrogen evolution reaction (HER) in water-alkaline electrolyzer
2017
In the field of water-alkaline electrolyzer, the development of nanoporous low cost nickel electrodes is one of the potential approaches to increase electrocatalytic activity. Template electrodeposition is a facile and cheap technique for obtaining Ni nanowires (NWs) with high surface area. These nanostructures were fabricated by a two-step procedure. In the first step, a Ni compact layer was deposited on one side of the template where a gold film was previously sputtered, while, in the second-step, an ordered array of Ni-NWs was obtained by electrodeposition inside the template channels. The NWs were firmly connected to the underlying Ni layer, acting as a current collector. In order to en…
Ni alloy nanowires as high efficiency electrode materialsnfor alkaline electrolysers
2020
Hydrogen production by water electrolysis (WE) is a very promising technology because it is a pollution-free process especially if renewable sources are employed to energy supply. Nowadays, the cost of hydrogen production by WE is higher than other available technologies, which makes WE not competitive. Many efforts have been made to improve WE performance, through the use of electrodes made of transition metal alloys as cathode and compound of metal oxide as anode [1]. In the field of water-alkaline electrolyzer, the development of cheap nanoporous based nickel electrodes with high electrocatalytic features is one of the potential approaches to increase the WE performance [2]. A facile met…
NiO thin film for mercury detection in water by square wave anodic stripping voltammetry
2017
NiO thin film thermally grown on Ni was investigated for the first time as an electrochemical sensor of mercury ions in water. The film was obtained by thermal oxidation in air of a commercial Ni foil. The influence of oxidation temperature, and time have been investigated by XRD, SEM, and EDS analysis. Square wave anodic stripping voltammetry was used for detecting Hg2+ ions in aqueous solution with different ion concentrations. In order to improve the response signal, all the operational parameters related to the sensing process such as pH, deposition time, potential, and square wave frequency, have been optimized. We obtained a detection limit of 4.4 ppb with a sensitivity of 1.1 µA ppb-…
Nanostructured Pb electrode for innovative lead-acid battery
2017
Lead-acid batteries are widely used for energy storage, due to a well-established and reliable technology. Over the years, various studies for improving the performance of this battery have been performed. The main goal is to replace conventional plates with innovative electrodes having good stability, high capacity and high surface area. In particular, it is necessary to improve the kinetics of electrochemical conversion reactions at the electrode-solution interface, and to guarantee good electrical continuity during repeated charge/discharge cycles. To achieve these goals, the attention was focused on nanostructured electrodes. Up-to-date, two principal approaches have been followed. In t…