Monofunctional metathesis polymers via sacrificial diblock copolymers.

End Capping Ring-Opening Olefin Metathesis Polymerization Polymers with Vinyl Lactones

The selective placement of a functional group at the chain end of a ring-opening metathesis polymer using ruthenium carbene initiators has been a significant limitation. Here we demonstrate a highly effective and facile end-capping technique for ROMP with living ruthenium carbene chain ends using single-turnover olefin metathesis substrates. Vinylene carbonate and 3H-furanone are introduced as functionalization and termination agents for the ruthenium-initiated ring-opening metathesis polymerization. This leads directly to the formation of functional polymer end groups without further chemical transformation steps. Aldehyde and carboxylic acid end groups can be introduced by this new method…

Monofunktionalisierte Metathesepolymere durch Abbau von Diblockcopolymeren