0000000000219504
AUTHOR
Stephen M. Winter
The Importance of Electronic Dimensionality in Multiorbital Radical Conductors
The exceptional performance of oxobenzene-bridged bis-1,2,3-dithiazolyls 6 as single-component neutral radical conductors arises from the presence of a low-lying π-lowest unoccupied molecular orbital, which reduces the potential barrier to charge transport and increases the kinetic stabilization energy of the metallic state. As part of ongoing efforts to modify the solid-state structures and transport properties of these so-called multiorbital materials, we report the preparation and characterization of the acetoxy, methoxy, and thiomethyl derivatives 6 (R = OAc, OMe, SMe). The crystal structures are based on ribbonlike arrays of radicals laced together by S···N′ and S···O′ secondary bondin…
The Importance of Electronic Dimensionality in Multiorbital Radical Conductors.
The exceptional performance of oxobenzene-bridged bis-1,2,3-dithiazolyls 6 as single-component neutral radical conductors arises from the presence of a low-lying π-lowest unoccupied molecular orbital, which reduces the potential barrier to charge transport and increases the kinetic stabilization energy of the metallic state. As part of ongoing efforts to modify the solid-state structures and transport properties of these so-called multiorbital materials, we report the preparation and characterization of the acetoxy, methoxy, and thiomethyl derivatives 6 (R = OAc, OMe, SMe). The crystal structures are based on ribbonlike arrays of radicals laced together by S···N' and S···O' secondary bondin…
CCDC 1902028: Experimental Crystal Structure Determination
Related Article: Aaron Mailman, Craig M. Robertson, Stephen M. Winter, Paul A. Dube, Richard T. Oakley|2019|Inorg.Chem.|58|6495|doi:10.1021/acs.inorgchem.9b00691
CCDC 1902030: Experimental Crystal Structure Determination
Related Article: Aaron Mailman, Craig M. Robertson, Stephen M. Winter, Paul A. Dube, Richard T. Oakley|2019|Inorg.Chem.|58|6495|doi:10.1021/acs.inorgchem.9b00691
CCDC 1902029: Experimental Crystal Structure Determination
Related Article: Aaron Mailman, Craig M. Robertson, Stephen M. Winter, Paul A. Dube, Richard T. Oakley|2019|Inorg.Chem.|58|6495|doi:10.1021/acs.inorgchem.9b00691