0000000000225091
AUTHOR
Birgit Gerke
Reactions with a Metalloid Tin Cluster {Sn10[Si(SiMe3)3]4}(2-): Ligand Elimination versus Coordination Chemistry.
Chemistry that uses metalloid tin clusters as a start- ing material is of fundamental interest towards understand- ing the reactivity of such compounds. Since we identified {Sn10(Si(SiMe3)3)4} 2� 7 as an ideal candidate for such reactions, we present a further step in the understanding of metalloid tin cluster chemistry. In contrast to germanium chemistry, ligand elimination seems to be a major reaction channel, which leads to the more open metalloid cluster {Sn10(Si(SiMe3)3)3} � 9, in which the Sn core is only shielded by three Si(SiMe3)3 ligands. Compound 9 is obtained through different routes and is crystallised together with two differ- ent countercations. Besides the structural charact…
CCDC 1044696: Experimental Crystal Structure Determination
Related Article: Claudio Schrenk, Birgit Gerke, Rainer Pöttgen, Andre Clayborne, Andreas Schnepf|2015|Chem.-Eur.J.|21|8222|doi:10.1002/chem.201500550
CCDC 1044697: Experimental Crystal Structure Determination
Related Article: Claudio Schrenk, Birgit Gerke, Rainer Pöttgen, Andre Clayborne, Andreas Schnepf|2015|Chem.-Eur.J.|21|8222|doi:10.1002/chem.201500550