0000000000230087

AUTHOR

Eleonora Ballerini

showing 2 related works from this author

ChemInform Abstract: Palladium Supported on Cross-Linked Imidazolium Network on Silica as Highly Sustainable Catalysts for the Suzuki Reaction under …

2013

3-Mercaptopropyl-modified silica-supported bis-imidazolium Pd-catalysts are developed and successfully utilized for Suzuki reactions.

Flow conditionschemistrySuzuki reactionChemical engineeringNetwork onchemistry.chemical_elementGeneral MedicineCatalysisPalladiumChemInform
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Palladium Supported on Cross-Linked Imidazolium Network on Silica as Highly Sustainable Catalysts for the Suzuki Reaction under Flow Conditions

2013

Highly cross-linked imidazolium-based materials, obtained by radical oligomerization of bis-vinylimidazolium salts in the presence of 3-mercaptopropyl-modified silica gel, were used as supports for palladium catalysts. Thanks to the high imidazolium loading these materials were able to support a high amount of the metal (10 wt%). Such materials were characterized by several techniques (13C magic angle spinning nuclear magnetic resonance, the Brunauer-Emmett-Teller technique, X-ray photoelectron spectroscopy, and transmission electron microscopy). The palladium catalysts displayed good activity allowing the synthesis of several biphenyl compounds in high yields working with only 0.1 mol% of …

Green chemistryflow chemistryInorganic chemistrychemistry.chemical_elementCatalysisMetalchemistry.chemical_compoundSuzuki reactionMagic angle spinningsustainable chemistry; catalysis flow chemistrysustainable chemistryC C couplingSuzuki-Miyaura reactioncatalyst recyclingBiphenylcatalysisSilica gelSettore CHIM/06 - Chimica OrganicaGeneral ChemistrypalladiumSuzuki–Miyaura reactionchemistryvisual_artvisual_art.visual_art_mediumC-C couplingPalladiumAdvanced Synthesis & Catalysis
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