Author: Leticia Giménez

0000000000236431

AUTHOR

Leticia Giménez

Polypyridyl-functionalizated alkynyl gold(i) metallaligands supported by tri- and tetradentate phosphanes

A series of alkynyl gold(I) tri and tetratopic metallaligands of the type [Au3(CuC-R)3(μ3-triphosphane)] (R = 2,2'-bipyridin-5-yl or C10H7N2, 2,2':6',2''-terpyridin-4-yl or C15H10N3; triphosphane = 1,1,1-tris(diphenylphosphanyl) ethane or triphos, 1,3,5-tris(diphenylphosphanyl)benzene or triphosph) and [Au4(CuC-R)4 (μ4-tetraphosphane)] (R = C10H7N2, C15H10N3; tetraphosphane = tetrakis(diphenylphosphanylmethyl)methane or tetraphos, 1,2,3,5-tetrakis(diphenylphosphanyl)benzene or tpbz, tetrakis(diphenylphosphaneylmethyl)-1,2- ethylenediamine or dppeda) were obtained in moderate to good yields. All complexes could be prepared by a Q4 reaction between the alkynyl gold(I) polymeric species [Au(Cu…

research product

CCDC 1561541: Experimental Crystal Structure Determination

Related Article: Montserrat Ferrer, Leticia Giménez, Albert Gutiérrez, João Carlos Lima, Manuel Martínez, Laura Rodríguez, Avelino Martín, Rakesh Puttreddy, Kari Rissanen|2017|Dalton Trans.|46|13920|doi:10.1039/C7DT02732J

research product

CCDC 1559283: Experimental Crystal Structure Determination

Related Article: Montserrat Ferrer, Leticia Giménez, Albert Gutiérrez, João Carlos Lima, Manuel Martínez, Laura Rodríguez, Avelino Martín, Rakesh Puttreddy, Kari Rissanen|2017|Dalton Trans.|46|13920|doi:10.1039/C7DT02732J

research product

PEPhysical Sciences and Engineering
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