0000000000241492

AUTHOR

Loredana Latterini

showing 4 related works from this author

Solvent-dependent hypsochromic shift in the imidazole based complex [Cu(µ2-SO4)(Im)4] and ameliorative effects on breast cancer-induced bone metastas…

2023

A sulfate-bridged complex [Cu(µ2-SO4)(Im)4] (1) was prepared and structurally characterized, where Im: imidazole. The X-ray structure analysis reveals that 1 crystallizes in the monoclinic system with space group C2/c. The octahedral coordination around the metal center is made up of four distinct imine nitrogen atoms in the equatorial plane, and two sulfate oxygen atoms occupying the axial sites. The covalent linkage between metals via the sulfate group, forming infinite 1D zigzag chains, ensures the entanglement of the structure. These chains, in turn, are further assembled into a 2D network through N-H...O hydrogen bonding. Thermal analyses underline the high thermal stability of our com…

antioksidantitimidazole-based complexesbreast cancersyöpäsolutantioxidant potentialbone metastasesbioaktiiviset yhdisteetGeneral Chemical Engineeringhypsochromic shiftkupariGeneral Chemistryoxidative damagekompleksiyhdisteet
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Design, Synthesis and Characterization of a Visible-Light-Sensitive Molecular Switch and Its PEGylation Towards a Self-Assembling Molecule.

2022

HBDI-like chromophores represent a novel set of biomimetic switches mimicking the fluorophore of the green fluorescent protein that are currently studied with the hope to expand the molecular switch/motor toolbox. However, until now members capable of absorbing visible light in their neutral (i. e. non-anionic) form have not been reported. In this contribution we report the preparation of an HBDI-like chromophore based on a 3-phenylbenzofulvene scaffold capable of absorbing blue light and photoisomerizing on the picosecond timescale. More specifically, we show that double-bond photoisomerization occurs in both the E-to-Z and Z-to-E directions and that these can be controlled by irradiating …

light-driven molecular switchesnanoaggregatesHBDI-like chromophores; light-driven molecular switches; light-sensitive molecules; nanoaggregates; photoswitches; self-assembling molecules; Green Fluorescent Proteins; LightLightOrganic ChemistryGreen Fluorescent ProteinsHBDI-like chromophoresself-assembling moleculesGeneral Chemistrylight-sensitive moleculesCatalysisphotoswitchesChemistry (Weinheim an der Bergstrasse, Germany)
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CCDC 2071148: Experimental Crystal Structure Determination

2021

Related Article: Marco Paolino, Mario Saletti, Annalisa Reale, Mariano Licciardi, Paola Varvarà, Arnaud Marquette, Jérémie Léonard, Claudia Bonechi, Alessandro Donati, Gianluca Giorgi, Germano Giuliani, Benedetta Carlotti, Fausto Ortica, Loredana Latterini, Mariangela Gentile, Eugenio Paccagnini, Massimo Olivucci, Andrea Cappelli|2022|Chem.-Eur.J.|28|e202201477|doi:10.1002/chem.202201477

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersethyl 6-methoxy-1-(2-oxopyrrolidin-3-ylidene)-3-phenyl-1H-indene-2-carboxylateExperimental 3D Coordinates
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CCDC 2158907: Experimental Crystal Structure Determination

2023

Related Article: Khouloud Hchicha, Elena Cambiotti, Hmed Ben-Nasr, Daniel Chappard, Matti Haukka, Loredana Latterini, Salem Elkahoui, Arif J. Siddiqui, Mejdi Snoussi, Mohd Adnan, Houcine Naïli, Riadh Badraoui|2023|Arab.J.Chem.|16||doi:10.1016/j.arabjc.2023.105002

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[tetrakis(mu-sulfato)-hexadecakis(1H-imidazole)-tetra-copper]Experimental 3D Coordinates
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