Author: Arthur D. Ziegler

0000000000246144

AUTHOR

Arthur D. Ziegler

showing 2 related works from this author

Glycidyltosylat: Die Polymerisation eines “nicht polymerisierbaren” Monomers ermöglicht eine universelle, polymeranaloge Funktionalisierung von Polye…

2019

ChemistryGeneral MedicineAngewandte Chemie

researchProduct

Glycidyl Tosylate: Polymerization of a “Non‐Polymerizable” Monomer permits Universal Post‐Functionalization of Polyethers

2019

Abstract Glycidyl tosylate appears to be a non‐polymerizable epoxide when nucleophilic initiators are used because of the excellent leaving group properties of the tosylate. However, using the monomer‐activated mechanism, this unusual monomer can be copolymerized with ethylene oxide (EO) and propylene oxide (PO), respectively, yielding copolymers with 7–25 % incorporated tosylate‐moieties. The microstructure of the copolymers was investigated via in situ 1H NMR spectroscopy, and the reactivity ratios of the copolymerizations have been determined. Quantitative nucleophilic substitution of the tosylate‐moiety is demonstrated for several examples. This new structure provides access to a librar…

Ethylene oxidering-opening polymerization010405 organic chemistryCommunicationLeaving groupEpoxideGeneral Chemistry010402 general chemistry01 natural sciencesRing-opening polymerizationCommunicationsCatalysis0104 chemical scienceschemistry.chemical_compoundMonomerchemistryPolymerizationpolyetherPolymer chemistryCopolymerNucleophilic substitutionRing‐Opening Polymerizationfunctionalizationpoly(ethylene oxide)poly(propylene oxide)Angewandte Chemie International Edition

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