0000000000249684

AUTHOR

Silvestro Antonio Ruffolo

showing 13 related works from this author

An integrated analytical approach to define the compositional and textural features of mortars used in the underwater archaeological site of castrum …

2019

This paper aims to carry out an archaeometric characterization of mortar samples taken from an underwater environment. The fishpond of the archaeological site of Castrum Novum (Santa Marinella, Rome, Italy) was chosen as a pilot site for experimentation. The masonry structures reached the maximum thickness at the apex of the fishpond (4.70 m) and consisted of a concrete conglomerate composed of slightly rough stones of medium size bound with non-hydraulic mortar. After sampling, for a complete characterization of selected mortar fragments, different and complementary techniques (stereomicroscopy, polarizing optical microscopy, and X-ray powder diffraction analysis) were carried out in order…

lcsh:QE351-399.2restoration02 engineering and technologyhydraulic-type mortars010502 geochemistry & geophysics01 natural sciencesUnderwater cultural heritageUnderwaterPozzolanaSettore GEO/09 -Georis. Miner.e Appl.Mineral.-Petrogr. per l'Ambi.ed i B.Cult.0105 earth and related environmental scienceslcsh:Mineralogybusiness.industrySampling (statistics)GeologyMasonryHydraulic-type mortars Minero-petrographic analysis Pozzolana Restoration021001 nanoscience & nanotechnologyGeotechnical Engineering and Engineering GeologyArchaeologyCharacterization (materials science)pozzolanaHomogeneousminero-petrographic analysisMortar0210 nano-technologybusinessGeology
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Antifouling Mortars for Underwater Restoration

2022

This research has focused on the assessment of the compositional features and mechanical and antifouling performances of two different mortars formulated for an underwater setting, and which contain Mg(OH)2 as an antifouling agent. Regarding the mechanical characterization, the uniaxial compressive strength and flexural strength were measured. The composition of the materials was explored by differential thermal/thermogravimetric analysis (DTA-TG), X-ray diffraction analysis (XRPD), and scanning electronic microscopy (SEM) coupled with EDS microanalysis. The assessment of the biological colonization was evaluated with colorimetric analysis and image analysis. The results suggest that both m…

restorationgeomaterialsbiofouling geomaterials magnesium hydroxide mortars nanoparticles restoration submerged sitesGeneral Chemical Engineeringbiofoulingsubmerged sitesPetrologíananoparticlesGeneral Materials Sciencemortarsmagnesium hydroxide; mortars; submerged sites; biofouling; geomaterials; restoration; nanoparticlesSettore GEO/09 -Georis. Miner.e Appl.Mineral.-Petrogr. per l'Ambi.ed i B.Cult.magnesium hydroxideNanomaterials
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Damage monitoring on carbonate stones: Field exposure tests contributing to pollution impact evaluation in two Italian sites

2017

During the last decades, many studies have been carried out on environmental monitoring in specific sites aiming at their protection and conservation; however, researches focused on the direct implications, in terms of quantitative evaluation of stone deterioration, of these monitoring actions are still scarce. This experimental work aims at monitoring the degradation processes affecting historical buildings constituted by carbonate stones. Specifically, specimens of Carrara marble and two limestones largely used in the Sicilian Baroque architecture, namely Noto and Comiso stones, were exposed outdoor in two Italian sites (Catania and Palermo), which are characterized by different environme…

Pollution010504 meteorology & atmospheric sciencesmedia_common.quotation_subjectAir pollutionAir pollution010501 environmental sciencesmedicine.disease_cause01 natural scienceschemistry.chemical_compoundDegradationair pollution ; building materials ; degradation ; particulate mater soluble fraction ; trace elementsEnvironmental monitoringmedicineGeneral Materials ScienceSoluble fractionInductively coupled plasma mass spectrometry0105 earth and related environmental sciencesmedia_commonCivil and Structural EngineeringTrace elementsChemistryMetallurgyBuilding and ConstructionParticulatesparticulate materDeposition (aerosol physics)Environmental chemistryBuilding materialsTrace elementCarbonate rockCarbonateBuilding materialMaterials Science (all)Particulate matter
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Laboratory tests addressed to realize customized restoration procedures of underwater archaeological ceramic finds

2013

The present contribution is part of a biennial research project funded by the Italian Ministry of Education, Universities and Research (MIUR). This study, currently in progress, deals with innovative experimental approaches applied to the chemical, mineralogical and physical transformations occurring during the prolonged permanence of archaeological ceramic finds in seawater environments as well as to restoration and conservation issues of the same underwater artifacts. The experimental approach used in this research consisted in the manufacture of ceramic test-pieces (briquettes) and their successive placing in underwater environment. This work aims at assessing how textural and compositio…

Pore sizeAbsorption of waterCapillary water absorptionkinetics of capillary water absorptionGeneral ChemistryArchaeologyexperimental firingpore size distributionarchaeological ceramicvisual_artvisual_art.visual_art_mediumEnvironmental scienceGeneral Materials ScienceSeawaterCeramicUnderwaterseawater burialMercury intrusion porosimetryPorositySettore GEO/09 -Georis. Miner.e Appl.Mineral.-Petrogr. per l'Ambi.ed i B.Cult.total porosityApplied Physics A
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Multidisciplinary approach to characterize archaeological materials and status of conservation of the Roman thermae of reggio Calabria Site (Calabria…

2020

This multidisciplinary research focuses on diagnostic investigations to characterize the archaeological materials, as well as the alteration and degradation forms detected at the Roman Thermae of Reggio Calabria (Calabria, South Italy) site. The thermal complex, (dating I–II century B.C.), was built around three main rooms such as the caldarium (hot bath), the tepidarium (warm bath) and the frigidarium (cold bath), all connected to a central room through several entrances. The central hall still preserves a suggestive mosaic floor dating between the II and III century A.D., characterized by geometric motifs and black and white tesserae. Fragments of various archaeological stone materials, s…

Reggio CalabriaRoman Thermae0211 other engineering and technologies02 engineering and technology010501 environmental sciencesCaldarium01 natural scienceslcsh:Technologyarchaeological materials; biological colonization; calcarenite; marble; mosaic tesserae; Roman Thermae; Reggio CalabriaMosaiclcsh:ChemistrycalcareniteArchaeological materialGeneral Materials Sciencemosaic tesseraearchaeological materials; biological colonization; calcarenite; marble; mosaic <i>tesserae</i>; Roman <i>Thermae</i>; Reggio CalabriaInstrumentationlcsh:QH301-705.5Archaeological materials Biological colonization Calcarenite Marble Mosaic tesserae Reggio Calabria Roman Thermae021101 geological & geomatics engineering0105 earth and related environmental sciencesFluid Flow and Transfer Processeslcsh:TProcess Chemistry and TechnologymarbleGeneral Engineeringarchaeological materials biological colonization calcarenite marble mosaic tesserae Roman Thermae Reggio CalabriaArchaeologylcsh:QC1-999Computer Science Applicationsmosaic <i>tesserae</i>Calcarenitelcsh:Biology (General)lcsh:QD1-999lcsh:TA1-2040Roman <i>Thermae</i>archaeological materialsbiological colonizationlcsh:Engineering (General). Civil engineering (General)Geologylcsh:Physics
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The CRATI project: New insights on the consolidation of saltweathered stone and the case study of San Domenico Church in Cosenza (South Calabria, Ita…

2019

This paper presents the results of a laboratory experimentation carried out on stone materials in the framework of the CRATI project (Knowledge and Restoration through Advanced Integrated Technologies) aimed at testing new products with consolidating properties by means of an integrated methodological approach. After the preliminary characterization of stone materials collected in the pilot site, the second stage of the activities within the project were focused on the formulation and testing of products for the conservation of the same materials against decay, especially salt crystallization, one of the most aggressive and common degrading processes. The San Domenico Church, located in the…

Materials science0211 other engineering and technologiesEnvironmental engineeringStone decayBiocalcarenite02 engineering and technologySurfaces and Interfaces010501 environmental sciencesHydrogen phosphateSoluble salt crystallization01 natural sciencesSurfaces Coatings and FilmsHydroxyapatitebiocalcareniteslcsh:TA1-2040Consolidation treatment021105 building & constructionbiocalcarenites stone decay soluble salt crystallization consolidation treatments hydroxyapatiteMaterials Chemistryconsolidation treatmentslcsh:Engineering (General). Civil engineering (General)Settore GEO/09 -Georis. Miner.e Appl.Mineral.-Petrogr. per l'Ambi.ed i B.Cult.Salt crystallization0105 earth and related environmental sciences
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Surface and volume non-invasive methods for the structural monitoring of the bass-relief ‘Madonna con Bambino’ (Gorizia, Northern Italy)

2016

Structural analysis of marble statues, carried out by non-invasive and in situ methods, is crucial to define the state of conservation of the artworks and to identify the deterioration phenomena that can affect them. In this work, we combined in situ non-destructive techniques, ultrasonic tomography (US), ultraviolet-induced visible fluorescence (UV-IF) and X-ray fluorescence (XRF) to study the bass-relief ‘Madonna con Bambino’ (Gorizia, Italy). The US revealed the presence of some metallic pivots, associated with areas of high sound velocity; moreover, a more degraded area has been identified in the lower part of the bass-relief. The acquired UV-IF image confirmed the presence of surface d…

Surface Propertiesultrasonic tomographyMineralogySculpturePlant Science01 natural sciencesBiochemistryFluorescenceCalcium CarbonateAnalytical ChemistryPlant scienceMethodsUV-IF010405 organic chemistryChemistrymarbleNon invasiveOrganic Chemistry0104 chemical sciencesNorthern italy010404 medicinal & biomolecular chemistryItalyNon-invasive methodUltrasonic TomographyInorganic materialsdeterioration phenomenaArtStructural monitoring
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Archaeometric Characterisation of Decorated Pottery from the Archaeological Site of Villa dei Quintili (Rome, Italy): Preliminary Study

2019

This work focused on the study of decorated pottery dated back to the 16th century from the Roman archaeological site of Villa dei Quintili, a monumental complex located in the south-eastern part of Rome (Italy). A minero-petrographic and geochemical study was undertaken to analyse five archaeological samples in order to define textural features and raw materials used for their production, along with the chemical and physical composition of the superficial decorative glazed coatings. For this purpose, different analytical methods were used, such as polarising optical microscope (POM), X-ray diffraction (XRD), micro-Raman spectroscopy, X-Ray fluorescence (XRF), and electron microprobe analys…

media_common.quotation_subject02 engineering and technologypetrographyPetrographyMajolica0601 history and archaeologymicro-Raman spectroscopySettore GEO/09 -Georis. Miner.e Appl.Mineral.-Petrogr. per l'Ambi.ed i B.Cult.Decorative glazed coatingmedia_common060102 archaeologyDecorative glazed coatings EMPA-EDS Micro-Raman spectroscopy Petrography Potterylcsh:QE1-996.5EMPA-EDSThe Renaissance06 humanities and the artsArtpottery021001 nanoscience & nanotechnologyArchaeologyMicro raman spectroscopylcsh:GeologyEnergy dispersive spectrometrydecorative glazed coatingsGeneral Earth and Planetary SciencesPottery0210 nano-technologyEarth and Planetary Sciences (all)
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Preliminary Study of the Mural Paintings of Sotterra Church in Paola (Cosenza, Italy)

2022

A multi-analytical approach was employed to study wall paintings located in the Sotterra church at Paola, in the province of Cosenza, Italy. The site is an underground church (hence the name of Sotterra, which means &ldquo;under the earth&rdquo;) rediscovered in the second half of the 19th century, during the building works of the Madonna del Carmine church on the same area. This underground church preserves valuable mural paintings having different styles. The construction&rsquo;s dating and overlapped modifications made until the site was abandoned is also debated. A wall painting, depicting &ldquo;The Virgin&rdquo; as part of the &ldquo;Annunciation and the Archangel Gabriel&rdquo; prese…

frescoes infrared imaging mural paintings non‐destructive analyses pigments Sotterra church stratigraphySotterra church; mural paintings; frescoes; non-destructive analyses; pigments; infrared imaging; stratigraphyGeneral Materials ScienceSettore GEO/09 -Georis. Miner.e Appl.Mineral.-Petrogr. per l'Ambi.ed i B.Cult.
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Multidisciplinary Approach for Evaluating the Geochemical Degradation of Building Stone Related to Pollution Sources in the Historical Center of Napl…

2020

Natural stones have represented one of the main building materials since ancient times. In recent decades, a worsening in degradation phenomena related mostly to environmental pollution was observed, threatening their conservation. The present work is focused on the minero-petrographic and geochemical characterization of black crust (BC) samples taken from the historical center of Naples, after selecting two pilot monumental areas. The latter were chosen based on their historical importance, type of material, state of preservation and position in the urban context (i.e., high vehicular traffic area, limited traffic area, industrial area, etc.). The building materials used and their interact…

Pollutionblack crust010504 meteorology & atmospheric sciencesmedia_common.quotation_subjectEarth scienceEnergy dispersionEnvironmental pollutionContext (language use)010501 environmental sciencesblack crusts; cultural heritage; marble; Naples pollution; heavy metals01 natural scienceslcsh:Technologyblack crusts cultural heritage marble Naples pollution heavy metalslcsh:ChemistryMultidisciplinary approachGeneral Materials Scienceheavy metalsInstrumentationlcsh:QH301-705.5Settore GEO/09 -Georis. Miner.e Appl.Mineral.-Petrogr. per l'Ambi.ed i B.Cult.0105 earth and related environmental sciencesmedia_commonFluid Flow and Transfer ProcessesNatural stonelcsh:TProcess Chemistry and TechnologyIndustrial areamarbleGeneral Engineeringcultural heritagelcsh:QC1-999Computer Science ApplicationsCharacterization (materials science)Naples pollutionlcsh:Biology (General)lcsh:QD1-999lcsh:TA1-2040Environmental scienceblack crustslcsh:Engineering (General). Civil engineering (General)lcsh:Physics
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New insights to assess the consolidation of stone materials used in built heritage: the case study of ancient graffiti (Tituli Picti) in the archaeol…

2020

AbstractTituli Picti are an ancient form of urban graffiti very common in the archaeological site of Pompeii (Naples, South—Italy). They are generally made of red pigments applied on walls of Campanian ignimbrite. This paper deals with a scientific investigation aimed to their conservation. This is a challenging task since it requires a multidisciplinary approach that includes restorers, archaeologists and conservation scientists. The study has provided suggestions on the proper way to conserve Tituli Picti over time. In the present work, several specimens of Campanian ignimbrite were painted with red earth pigment; lime and Arabic gum have been used as binders as well. Such painted stones …

Archeologylcsh:QD71-142lcsh:Fine ArtsConsolidation (soil)Conservation Consolidation Tituli Picti of PompeiiArabicTituli Picti of Pompeii010401 analytical chemistrylcsh:Analytical chemistryThermal agingConservationTituli Picti of Pompeii Conservation Consolidation010502 geochemistry & geophysicsGraffiti01 natural sciencesArchaeologylanguage.human_language0104 chemical sciencesScotch tapelanguagelcsh:NBuilt heritageSettore GEO/09 -Georis. Miner.e Appl.Mineral.-Petrogr. per l'Ambi.ed i B.Cult.Consolidation0105 earth and related environmental sciences
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Comparative study of protective coatings for the conservation of Urban Art

2020

Abstract Contemporary mural paintings are complex artworks for several reasons, including the heterogeneity of the materials used to make them, and the different types of substrate on which the painting layers can be applied. Currently we are focused on a technical-scientific research aimed to solve the issues related to the long-term care and maintenance of murals, by evaluating the performance of several protective coatings applied on these artworks. This paper deals with a preliminary experimentation aimed to: (a) study the interaction of antigraffiti products on common synthetic paints; (b) test the effectiveness and efficiency of several commercial products used as antigraffiti; (c) de…

Antigraffiti Protection Street art ArtworkArcheologyPaintingMaterials scienceProtectionMaterials Science (miscellaneous)010401 analytical chemistryNanotechnology02 engineering and technologyConservationSubstrate (printing)021001 nanoscience & nanotechnology01 natural sciencesAntigraffiti0104 chemical sciencesCoated surfaceChemistry (miscellaneous)Street art Artwork0210 nano-technologyGeneral Economics Econometrics and FinanceSpectroscopy
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Additional file 1 of New insights to assess the consolidation of stone materials used in built heritage: the case study of ancient graffiti (Tituli P…

2020

Additional file 1: Table S1. Summary of the consolidation treatments carried out on the painted specimens. Figure S1. Arrangement of the washout test, samples were immersed in deionized water and a vortex were generated by means of a magnetic stirrer.

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