0000000000249719

AUTHOR

Arnita Spule

0000-0002-4717-7474

showing 3 related works from this author

Identifying Iron-Bearing Nanoparticle Precursor for Thermal Transformation into the Highly Active Hematite Photo-Fenton Catalyst

2020

Funding: This reseach was funded by the European Regional Development Fund within the Activity 1.1.1.2 “Post-doctoral Research Aid” of the Specific Aid Objective 1.1.1 “To increase the research and innovative capacity of scientific institutions of Latvia and the ability to attract external financing, investing in human resources and infrastructure” of the Operational Programme “Growth and Employment” (No. 1.1.1.2/VIAA/1/16/157).

inorganic chemicalsPhoto-FentonGoethiteMaterials scienceHematiteNanoparticlelcsh:Chemical technology010402 general chemistry01 natural sciences7. Clean energyCatalysishematiteCatalysislcsh:Chemistryphoto-Fenton:NATURAL SCIENCES:Physics [Research Subject Categories]Goethitegoethitelcsh:TP1-1185Reactivity (chemistry)Physical and Theoretical ChemistryAqueous solutionWater purification010405 organic chemistryHematite0104 chemical sciencesAmorphous solidlcsh:QD1-999Chemical engineering13. Climate actionvisual_artvisual_art.visual_art_mediumwater purificationVisible spectrumCatalysts
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Sol-gel auto-combustion synthesis of Ca2Fe2O5 brownmillerite nanopowders and thin films for advanced oxidation photoelectrochemical water treatment i…

2019

Abstract This study describes a straightforward Ca2Fe2O5 brownmillerite nanopowder and thin film synthesis by the water-based sol-gel auto-combustion method. The material characterization results confirmed the phase pure narrow bandgap Ca2Fe2O5 nanoparticle formation. The surface area of synthesized nanopowder was 13.55 m2/g. Powders at loading 1 g/l exhibit high visible light photocatalytic activity by degrading 10 mg/l methylene blue in water in 120 min confirmed by total organic carbon studies. The high visible light photocatalytic activity is related to Ca2Fe2O5 narrow band gap and high reduction potential of its conduction band which triggers the formation of superoxide radical ∙ O 2 -…

Materials scienceBand gapProcess Chemistry and TechnologyNanoparticle02 engineering and technology010501 environmental sciencesengineering.material021001 nanoscience & nanotechnology01 natural sciencesPollutionReaction rate constantChemical engineeringPhotocatalysisengineeringChemical Engineering (miscellaneous)BrownmilleriteThin film0210 nano-technologyWaste Management and Disposal0105 earth and related environmental sciencesVisible spectrumSol-gelJournal of Environmental Chemical Engineering
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Rapid Catalytic Water Disinfection from Earth Abundant Ca 2 Fe 2 O 5 Brownmillerite

2021

Water disinfection is a crucial challenge for humanity. Approaches that are effective, cheap, environmentally friendly, and do not promote gene exchange between bacteria are urgently required. Strongly oxidizing radicals are highly promising to achieve this as they lead to bacterial activation at high efficiencies. However, sources to consistently generate these radicals are limited to high energy UV/H2O2 treatments requiring a large energy input. Here the use of abundant, cheap, brownmillerite (Ca2Fe2O5) is demonstrated as an efficient radical generation material under dark conditions, showing a seven order of magnitude decrease in bacterial concentration over 10 min. This decrease is attr…

Renewable Energy Sustainability and the EnvironmentChemistryRadicalengineering.materialPulp and paper industryEnvironmentally friendlyCatalysischemistry.chemical_compoundOxidizing agentengineeringBrownmilleriteHydroxyl radicalWater disinfectionSludgeGeneral Environmental ScienceAdvanced Sustainable Systems
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