Author: Utpal Ghosh

0000000000255942

AUTHOR

Utpal Ghosh

New cyclic tetranuclear copper(II) complexes containing quadrilateral cores: Synthesis, structure, spectroscopy and their interactions with DNA in aqueous solution

Abstract Three new cyclic tetranuclear copper(II) complexes, Tetrakis{3-[(2-pyridylmethyl)-amino]-propionato}(tetrachloro)tetracopper(II)methanolhydrate (1·CH3OH·H2O), Tetrakis{3-[(2-pyridylmethyl)-amino]-propionato}(tetrathiocyanato)tetracopper(II) (2) and Tetrakis{3-[(2-pyridylmethyl)-amino]-propionato}(tetraazido)tetracopper(II) (3) have been synthesized by exploiting the chelating ability and bridging potential of a carboxyamine functionalized tridentate ligand, HL (HL = 3-[(2-Pyridylmethyl)-amino]-propionic acid). Complexes 1, 2 and 3 have been synthesized by carrying out reaction of the ligand HL with stoichiometric amounts of CuCl2·2H2O, CuCl2·2H2O/NH4SCN, and CuCl2·2H2O/NaN3, respec…

research product

CCDC 1484277: Experimental Crystal Structure Determination

Related Article: Gopal C. Giri, Shobhraj Haldar, Aloke Kumar Ghosh, Priyanka Chowdhury, Luca Carrella, Utpal Ghosh, Manindranath Bera|2017|J.Mol.Struct.|1142|175|doi:10.1016/j.molstruc.2017.04.033

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