Author: Rakesh Debnath

0000000000266271

AUTHOR

Rakesh Debnath

showing 3 related works from this author

Ligand mediated structural diversity of copper(II)-azido moiety: Synthesis, structure and magnetic study

2022

Abstract Two copper azido complexes [Cu4(L1)4(µ1,1-N3)3(N3)] (1) and [{Cu2(L2)(N-benzylen)(µ1,1-N3)3(µ1,1,3-N3(N3)]n (2) have been synthesized by the reaction of aqueous solution of sodium azide to a methanolic solution of copper perchlorate hexahydrate and corresponding Schiff-base ligands. Schiff bases HL1 and HL2 act as blocking coligands are derived from the 1:1 condensation of N-benzyl ethylenediamine with Salicyldehyde and 2-hydroxy-5-chloroacetophenone respectively (N-benzylen is the N-benzyl ethylenediamine). These two complexes are characterized by the elemental analysis, FT-IR, single crystal X-ray diffraction, powder XRD and also TGA. Single crystal X-ray structural study reveals…

Ligandchemistry.chemical_elementEthylenediamineCopperMagnetic susceptibilityInorganic ChemistryCrystallographyPerchloratechemistry.chemical_compoundchemistryTetramerMaterials ChemistryMoietyPhysical and Theoretical ChemistrySingle crystalInorganica Chimica Acta

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CCDC 2021182: Experimental Crystal Structure Determination

2021

Related Article: Mrinmoy Ghosh, Partha Pratim Chakrabarty, Atish Dipankar Jana, Dieter Schollmeyer, Hiroshi Sakiyama, Masahiro Mikuriya, Rakesh Debnath, Paula Brand��o, Dasarath Mal, Sandip Saha|2022|Inorg.Chim.Acta|531|120713|doi:10.1016/j.ica.2021.120713

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterstris(mu-azido)-tetrakis(2-({[2-(benzylamino)ethyl]imino}methyl)phenolato)-azido-tetra-copper(ii)Experimental 3D Coordinates

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CCDC 2021183: Experimental Crystal Structure Determination

2021

Related Article: Mrinmoy Ghosh, Partha Pratim Chakrabarty, Atish Dipankar Jana, Dieter Schollmeyer, Hiroshi Sakiyama, Masahiro Mikuriya, Rakesh Debnath, Paula Brand��o, Dasarath Mal, Sandip Saha|2022|Inorg.Chim.Acta|531|120713|doi:10.1016/j.ica.2021.120713

Space GroupCrystallographyCrystal SystemCrystal Structurecatena-[bis(mu-azido)-(azido)-(2-(1-{[2-(benzylamino)ethyl]imino}ethyl)-4-chlorophenolato)-(N1-benzylethane-12-diamine)-di-copper(ii)]Cell ParametersExperimental 3D Coordinates

researchProduct

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