0000000000270464

AUTHOR

P. J. Bereciartua

showing 7 related works from this author

Isoreticular two-dimensional magnetic coordination polymers prepared through pre-synthetic ligand functionalization

2018

Chemical functionalization is a powerful approach to tailor the physical and chemical properties of two-dimensional (2D) materials, increase their processability and stability, tune their functionalities and, even, create new 2D materials. This is typically achieved through post-synthetic functionalization by anchoring molecules on the surface of an exfoliated 2D crystal, but it inevitably alters the long-range structural order of the material. Here we present a pre-synthetic approach that allows the isolation of crystalline, robust and magnetic functionalized monolayers of coordination polymers. A series of five isostructural layered magnetic coordination polymers based on Fe(ii) centres a…

chemistry.chemical_classificationSolucions polimèriquesChemistryLigandMagnetismGeneral Chemical EngineeringNanotechnology02 engineering and technologyGeneral ChemistryPolymerCiència dels materials010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesExfoliation joint0104 chemical sciencesMonolayerSurface modificationMoleculeIsostructural0210 nano-technologyNature Chemistry
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Defect-Free Chemical Functionalization of Magnetic Monolayers Based on Coordination Polymers

2018

<p>Chemical functionalization has demonstrated to be a powerful approach to tailor the physical and chemical properties of two-dimensional (2D) materials, to increase their processability and</p> <p>stability, to add new functionalities and, even, to create new 2D materials. However, this post synthetic method – which involves the anchoring of molecules on the surface of an exfoliated 2D crystal – inevitably leads to defective materials, which lack long-range structural order. If defect-free functionalized monolayers are required, a radically new approach needs to be developed. Here we present a pre-synthetic method based on coordination chemistry that affords the isolatio…

chemistry.chemical_classificationchemistry.chemical_compoundMembraneMaterials scienceFerrocenechemistryLigandMonolayerMoleculeSurface modificationNanotechnologyPolymerCoordination complex
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CCDC 1849147: Experimental Crystal Structure Determination

2018

Related Article: J. López-Cabrelles, S. Mañas-Valero, I. J. Vitóriza-Yrezábal, P. J. Bereciartua, J. A. Rodríguez-Velamazán, J. C. Waerenborgh, B. J. C. Vieira, D. Davidovikj, P. G. Steeneken, H. S. J. van der Zant, G. Mínguez Espallargas, E. Coronado|2018|Nature Chemistry|10|1001|doi:10.1038/s41557-018-0113-9

Space GroupCrystallographyCrystal Systemcatena-[bis(mu-5-bromo-1H-benzimidazolato)-iron]Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1582347: Experimental Crystal Structure Determination

2018

Related Article: J. López-Cabrelles, S. Mañas-Valero, I. J. Vitóriza-Yrezábal, P. J. Bereciartua, J. A. Rodríguez-Velamazán, J. C. Waerenborgh, B. J. C. Vieira, D. Davidovikj, P. G. Steeneken, H. S. J. van der Zant, G. Mínguez Espallargas, E. Coronado|2018|Nature Chemistry|10|1001|doi:10.1038/s41557-018-0113-9

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[bis(mu-5-methyl-1H-benzimidazolato)-iron]Experimental 3D Coordinates
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CCDC 1582349: Experimental Crystal Structure Determination

2018

Related Article: J. López-Cabrelles, S. Mañas-Valero, I. J. Vitóriza-Yrezábal, P. J. Bereciartua, J. A. Rodríguez-Velamazán, J. C. Waerenborgh, B. J. C. Vieira, D. Davidovikj, P. G. Steeneken, H. S. J. van der Zant, G. Mínguez Espallargas, E. Coronado|2018|Nature Chemistry|10|1001|doi:10.1038/s41557-018-0113-9

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[bis(mu-6-aminobenzimidazol-1-ato)-iron]Experimental 3D Coordinates
researchProduct

CCDC 1582350: Experimental Crystal Structure Determination

2018

Related Article: J. López-Cabrelles, S. Mañas-Valero, I. J. Vitóriza-Yrezábal, P. J. Bereciartua, J. A. Rodríguez-Velamazán, J. C. Waerenborgh, B. J. C. Vieira, D. Davidovikj, P. G. Steeneken, H. S. J. van der Zant, G. Mínguez Espallargas, E. Coronado|2018|Nature Chemistry|10|1001|doi:10.1038/s41557-018-0113-9

Space GroupCrystallographycatena-[bis(mu-5-chloro-1H-benzimidazolato)-iron]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1582348: Experimental Crystal Structure Determination

2018

Related Article: J. López-Cabrelles, S. Mañas-Valero, I. J. Vitóriza-Yrezábal, P. J. Bereciartua, J. A. Rodríguez-Velamazán, J. C. Waerenborgh, B. J. C. Vieira, D. Davidovikj, P. G. Steeneken, H. S. J. van der Zant, G. Mínguez Espallargas, E. Coronado|2018|Nature Chemistry|10|1001|doi:10.1038/s41557-018-0113-9

catena-[bis(mu-1H-benzimidazolato)-iron]Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct