0000000000270469

AUTHOR

H. S. J. Van Der Zant

showing 8 related works from this author

Isoreticular two-dimensional magnetic coordination polymers prepared through pre-synthetic ligand functionalization

2018

Chemical functionalization is a powerful approach to tailor the physical and chemical properties of two-dimensional (2D) materials, increase their processability and stability, tune their functionalities and, even, create new 2D materials. This is typically achieved through post-synthetic functionalization by anchoring molecules on the surface of an exfoliated 2D crystal, but it inevitably alters the long-range structural order of the material. Here we present a pre-synthetic approach that allows the isolation of crystalline, robust and magnetic functionalized monolayers of coordination polymers. A series of five isostructural layered magnetic coordination polymers based on Fe(ii) centres a…

chemistry.chemical_classificationSolucions polimèriquesChemistryLigandMagnetismGeneral Chemical EngineeringNanotechnology02 engineering and technologyGeneral ChemistryPolymerCiència dels materials010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesExfoliation joint0104 chemical sciencesMonolayerSurface modificationMoleculeIsostructural0210 nano-technologyNature Chemistry
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Phase Transitions in Spin-Crossover Thin Films Probed by Graphene Transport Measurements

2016

Future multi-functional hybrid devices might combine switchable molecules and 2D material-based devices. Spin-crossover compounds are of particular interest in this context since they exhibit bistability and memory effects at room temperature while responding to numerous external stimuli. Atomically-thin 2D materials such as graphene attract a lot of attention for their fascinating electrical, optical, and mechanical properties, but also for their reliability for room-temperature operations. Here, we demonstrate that thermally-induced spin-state switching of spin-crossover nanoparticle thin films can be monitored through the electrical transport properties of graphene lying underneath the f…

Materials scienceFOS: Physical sciencesPhysics::OpticsBioengineeringContext (language use)Nanotechnology02 engineering and technologyDielectric010402 general chemistry01 natural scienceslaw.inventionlawMesoscale and Nanoscale Physics (cond-mat.mes-hall)General Materials ScienceThin filmCondensed Matter - Mesoscale and Nanoscale PhysicsGrapheneMechanical EngineeringMolecular electronicsGeneral Chemistry021001 nanoscience & nanotechnologyCondensed Matter Physics0104 chemical sciences3. Good healthCharge carrier0210 nano-technologyBilayer grapheneGraphene nanoribbonsNano Letters
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Ground-state spin blockade in a single-molecule junction

2019

It is known that the quantum mechanical ground state of a nanoscale junction has a significant impact on its electrical transport properties. This becomes particularly important in transistors consisting of a single molecule. Because of strong electron-electron interactions and the possibility of accessing ground states with high spins, these systems are eligible hosts of a current-blockade phenomenon called a ground-state spin blockade. This effect arises from the inability of a charge carrier to account for the spin difference required to enter the junction, as that process would violate the spin selection rules. Here, we present a direct experimental demonstration of a ground-state spin …

PhysicsCondensed Matter - Mesoscale and Nanoscale PhysicsCondensed matter physicsSpinsTransistorFOS: Physical sciencesQuàntums Teoria delsGeneral Physics and AstronomyCharge (physics)02 engineering and technology021001 nanoscience & nanotechnologyCondensed Matter::Mesoscopic Systems and Quantum Hall Effect01 natural sciencesPartícules (Física nuclear)law.inventionlawElectric fieldMesoscale and Nanoscale Physics (cond-mat.mes-hall)0103 physical sciencesCharge carrier010306 general physics0210 nano-technologyGround stateQuantumSpin-½
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CCDC 1849147: Experimental Crystal Structure Determination

2018

Related Article: J. López-Cabrelles, S. Mañas-Valero, I. J. Vitóriza-Yrezábal, P. J. Bereciartua, J. A. Rodríguez-Velamazán, J. C. Waerenborgh, B. J. C. Vieira, D. Davidovikj, P. G. Steeneken, H. S. J. van der Zant, G. Mínguez Espallargas, E. Coronado|2018|Nature Chemistry|10|1001|doi:10.1038/s41557-018-0113-9

Space GroupCrystallographyCrystal Systemcatena-[bis(mu-5-bromo-1H-benzimidazolato)-iron]Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1582347: Experimental Crystal Structure Determination

2018

Related Article: J. López-Cabrelles, S. Mañas-Valero, I. J. Vitóriza-Yrezábal, P. J. Bereciartua, J. A. Rodríguez-Velamazán, J. C. Waerenborgh, B. J. C. Vieira, D. Davidovikj, P. G. Steeneken, H. S. J. van der Zant, G. Mínguez Espallargas, E. Coronado|2018|Nature Chemistry|10|1001|doi:10.1038/s41557-018-0113-9

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[bis(mu-5-methyl-1H-benzimidazolato)-iron]Experimental 3D Coordinates
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CCDC 1582349: Experimental Crystal Structure Determination

2018

Related Article: J. López-Cabrelles, S. Mañas-Valero, I. J. Vitóriza-Yrezábal, P. J. Bereciartua, J. A. Rodríguez-Velamazán, J. C. Waerenborgh, B. J. C. Vieira, D. Davidovikj, P. G. Steeneken, H. S. J. van der Zant, G. Mínguez Espallargas, E. Coronado|2018|Nature Chemistry|10|1001|doi:10.1038/s41557-018-0113-9

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[bis(mu-6-aminobenzimidazol-1-ato)-iron]Experimental 3D Coordinates
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CCDC 1582350: Experimental Crystal Structure Determination

2018

Related Article: J. López-Cabrelles, S. Mañas-Valero, I. J. Vitóriza-Yrezábal, P. J. Bereciartua, J. A. Rodríguez-Velamazán, J. C. Waerenborgh, B. J. C. Vieira, D. Davidovikj, P. G. Steeneken, H. S. J. van der Zant, G. Mínguez Espallargas, E. Coronado|2018|Nature Chemistry|10|1001|doi:10.1038/s41557-018-0113-9

Space GroupCrystallographycatena-[bis(mu-5-chloro-1H-benzimidazolato)-iron]Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1582348: Experimental Crystal Structure Determination

2018

Related Article: J. López-Cabrelles, S. Mañas-Valero, I. J. Vitóriza-Yrezábal, P. J. Bereciartua, J. A. Rodríguez-Velamazán, J. C. Waerenborgh, B. J. C. Vieira, D. Davidovikj, P. G. Steeneken, H. S. J. van der Zant, G. Mínguez Espallargas, E. Coronado|2018|Nature Chemistry|10|1001|doi:10.1038/s41557-018-0113-9

catena-[bis(mu-1H-benzimidazolato)-iron]Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct