0000000000276258
AUTHOR
Alain Faure
showing 3 related works from this author
A KInetic Database for Astrochemistry (KIDA)
2012
We present a novel chemical database for gas-phase astrochemistry. Named the KInetic Database for Astrochemistry (KIDA), this database consists of gas-phase reactions with rate coefficients and uncertainties that will be vetted to the greatest extent possible. Submissions of measured and calculated rate coefficients are welcome, and will be studied by experts before inclusion into the database. Besides providing kinetic information for the interstellar medium, KIDA is planned to contain such data for planetary atmospheres and for circumstellar envelopes. Each year, a subset of the reactions in the database (kida.uva) will be provided as a network for the simulation of the chemistry of dense…
Rotational excitation of mono- and doubly-deuterated water by hydrogen molecules
2011
Rate coefficients for rotational transitions in HDO and D2O induced by H2 collisions below 300 K are presented. Calculations have been performed at the close-coupling and coupledstates levels with the deuterated variants of the H2O–H2 interaction potential of Valiron et al. The HDO–H2 and D2O–H2 rate coefficients are compared to the corresponding rate coefficients for HDO–He and H2O–H2, respectively. Significant differences are observed. In particular the new HDO rate coefficients are found to be significantly larger (by up to three orders of magnitude) than the corresponding HDO–He rate coefficients. The impact of the new HDO rate coefficients is examined with the help of non-LTE radiative…
Analyzing observations of molecules in the ISM: Theoretical and experimental studies of energy transfer
2012
Our laboratories have recently calculated a set of collision coefficients characterizing the efficiency of energy transfer between helium and/or hydrogen and a large variety of interstellar molecules. We have considered with molecules ranging from light hydrides, observed by the Herschel Space Observatory, to medium size molecules, observed by mm antennas, to heavy complex organic molecules, observed also in the cm range. We present a review of recent theoretical results obtained in our laboratories, for various kinds of commonly observed molecules.