0000000000280468
AUTHOR
Anisur Rahman Khuda-bukhsh
Water‐Soluble Heteronuclear [NaCu II 6 ] Metallomacrocyclic Sandwich Complexes: Synthesis, Structure, Properties and In Vitro Biological Studies
The water-soluble heteronuclear metallomacrocyclic sandwich clusters [NaCu6(hpnbpda)3(OH)3(OH2)3](NO3)·4H2O (1), [NaCu6(hpnbpda)3(OH)3(OH2)3](ClO4) (2), and [NaCu6(hpnbpda)3(OH)3(OH2)3](PF6) (3) [H3hpnbpda = N,N′-bis(2-pyridylmethyl)-2-hydroxy-1,3-propanediamine-N,N′-diacetic acid] have been synthesized in methanol at room temperature and fully characterized using several analytical techniques including single-crystal X-ray diffraction. The molecular architecture of complex 1 is built from the template assembly of three dinuclear [Cu2(hpnbpda)]+ fragments through their weak oxophillic interactions with a central sodium(I) cation. A close analysis of the single-crystal X-ray structure reveal…
CCDC 861462: Experimental Crystal Structure Determination
Related Article: Ayan Patra, Santu Kumar Saha, Tamal K. Sen, Luca Carrella, Ghezai T. Musie, Anisur Rahman Khuda-Bukhsh, Manindranath Bera|2014|Eur.J.Inorg.Chem.||5217|doi:10.1002/ejic.201402582