0000000000283340
AUTHOR
Timothy Johnson
PBI mixed matrix hollow fiber membrane: Influence of ZIF-8 filler over H2/CO2 separation performance at high temperature and pressure
High performance and commercially attractive mixed-matrix membranes were developed for H2/CO2 separation via a scalable hollow fiber spinning process. Thin (~300 nm) and defect-free selective layers were successfully created with a uniform distribution of the nanosized (~60 nm) zeolitic-imidazole framework (ZIF-8) filler within the polymer (polybenzimidazole, PBI) matrix. These membranes were able to operate at high temperature (150 °C) and pressure (up to 30 bar) process conditions required in treatment of pre-combustion and syngas process gas streams. Compared with neat PBI hollow fibers, filler incorporation into the polymer matrix leads to a strong increase in H2 permeance from 65 GPU t…
Compilation and Evaluation of Beta-Delayed Neutron Emission Probabilities and Half-Lives for Z > 28 Precursors
Abstract We present a compilation and evaluation of experimental β-delayed neutron emission probabilities (Pn) and half-lives (T1/2) for known or potential β-delayed neutron precursors with atomic number Z > 28 (73Cu–233Fr). This article includes the recommended values of both of these quantities, together with a compilation of experimental measurements when available. Some notable cases, as well as proposed standards for β-delayed neutron measurements are also discussed. Evaluated data has also been compared to systematics using three different approaches. The literature cut-off date for this work is August 15, 2020.