0000000000284754
AUTHOR
Michel Herman
showing 6 related works from this author
High-Resolution Spectroscopy and Preliminary Global Analysis of C–H Stretching Vibrations of C2H4 in the 3000 and 6000 cm-1 Regions
2010
International audience; Ethylene (ethene, H2C=CH2) is a naturally occurring compound in ambient air that affects atmospheric chemistry and global climate. The C2H4 spectrum is available in databases only for the 1000 and 3000 cm−1 ranges. In this work, the ethylene absorption spectrum was measured in the 6030- 6250 cm−1 range with the use of a high resolution Bruker IFS 125HR Fourierspectrometer and a two-channel opto-acoustic spectrometer with a diode laser. As a secondary standard of wavelengths, the methane absorption spectrum was used in both cases. A preliminary analysis was realized thanks to the tensorial formalism developed by the Dijon group that is implemented in the XTDS software…
The 2009 Edition of the GEISA Spectroscopic Database
2011
The updated 2009 edition of the spectroscopic database GEISA (Gestion et Etude des Informations Spectroscopiques Atmosphériques; Management and Study of Atmospheric Spectroscopic Information) is described in this paper. GEISA is a computer-accessible system comprising three independent sub-databases devoted, respectively, to: line parameters, infrared and ultraviolet/visible absorption cross-sections, microphysical and optical properties of atmospheric aerosols. In this edition, 50 molecules are involved in the line parameters sub-database, including 111 isotopologues, for a total of 3,807,997 entries, in the spectral range from 10-6 to 35,877.031cm-1.The successful performances of the new …
High-Resolution Jet-Cooled Spectroscopy of SF6: The ν2+ ν6Combination Band of32SF6and the ν3Band of the Rare Isotopomers
1998
The Fourier transform infrared spectrum of SF6 was recorded in a supersonic expansion jet of an SF6/argon mixture. The SF6:Ar seeding ratio was 2:3. The instrumental bandwidth was 0.005 cm-1. A globar source and an MCT detector were used. A rotational temperature of approximately 30 K was achieved. The nu2 + nu6 combination band of 32SF6 was analyzed using a modified version of the spherical top data system (STDS) programs developed in Dijon. A very good fit was obtained for this band with an rms of 0.0036 cm-1. The effective Hamiltonian was developed up to fourth order for the nu2 + nu6 part, to second order for the nu2 and ground state parts, and to first order for the nu6 part. Five hund…
22nd Colloquium on High Resolution Molecular Spectroscopy: Special Issue dedicated to Gianfranco Di Lonardo
2011
This issue, together with a second issue to appear in early 2012, consists of contributions submitted by participants attending the Colloquium on High Resolution Molecular Spectroscopy (HRMS), held in Dijon, France from 29 August to 2 September 2011. This is the 22nd in a biannual series of international conferences, which in recent years have taken place alternately in Dijon, France (1999, 2003, 2007, 2011) and in another European Country (1997 in Glasgow, Scotland; 2001 in Nijmegen, The Netherlands; 2005 in Salamanca, Spain, 2009 in Castellammare di Stabia, Italy). This series has a longstanding tradition as one of the most important conferences worldwide on all aspects of high resolution…
High-resolution spectroscopy and preliminary global analysis of C–H stretching vibrations of C2H4 in the 3000 and 6000cm−1 regions
2010
Abstract Ethylene (ethene, H2C=CH2) is a naturally occurring compound in ambient air that affects atmospheric chemistry and global climate. The C2H4 spectrum is available in databases only for the 1000 and 3000 cm−1 ranges. In this work, the ethylene absorption spectrum was measured in the 6030–6250 cm−1 range with the use of a high resolution Bruker IFS 125HR Fourier-spectrometer and a two-channel opto-acoustic spectrometer with a diode laser. As a secondary standard of wavelengths, the methane absorption spectrum was used in both cases. A preliminary analysis was realized thanks to the tensorial formalism developed by the Dijon group that is implemented in the XTDS software package [39] .…