0000000000289238

AUTHOR

F. Javier Valverde-muñoz

Chiral and Racemic Spin Crossover Polymorphs in a Family of Mononuclear Iron(II) Compounds

[EN] Understanding the origin of cooperativity and the equilibrium temperature of transition (T1/2) displayed by the spin-crossover (SCO) compounds as well as controlling these parameters are of paramount importance for future applications. For this task, the occurrence of polymorphism, presented by a number of SCO complexes, may provide deep insight into the influence of the supramolecular organization on the SCO behavior. In this context, herein we present a novel family of mononuclear octahedral FeII complexes with formula cis- [Fe(bqen)(NCX)2], where bqen is the chelating tetradentate ligand N,N¿-bis(8-quinolyl)ethane-1,2-diamine and X = S, Se. Depending on the preparation method, these…

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CCDC 1572177: Experimental Crystal Structure Determination

Related Article: Carlos Bartual-Murgui, Lucía Piñeiro-López, F. Javier Valverde-Muñoz, M. Carmen Muñoz, Maksym Seredyuk, José Antonio Real|2017|Inorg.Chem.|56|13535|doi:10.1021/acs.inorgchem.7b02272

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CCDC 1572180: Experimental Crystal Structure Determination

Related Article: Carlos Bartual-Murgui, Lucía Piñeiro-López, F. Javier Valverde-Muñoz, M. Carmen Muñoz, Maksym Seredyuk, José Antonio Real|2017|Inorg.Chem.|56|13535|doi:10.1021/acs.inorgchem.7b02272

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CCDC 1572183: Experimental Crystal Structure Determination

Related Article: Carlos Bartual-Murgui, Lucía Piñeiro-López, F. Javier Valverde-Muñoz, M. Carmen Muñoz, Maksym Seredyuk, José Antonio Real|2017|Inorg.Chem.|56|13535|doi:10.1021/acs.inorgchem.7b02272

research product

CCDC 1572184: Experimental Crystal Structure Determination

Related Article: Carlos Bartual-Murgui, Lucía Piñeiro-López, F. Javier Valverde-Muñoz, M. Carmen Muñoz, Maksym Seredyuk, José Antonio Real|2017|Inorg.Chem.|56|13535|doi:10.1021/acs.inorgchem.7b02272

research product

CCDC 1572181: Experimental Crystal Structure Determination

Related Article: Carlos Bartual-Murgui, Lucía Piñeiro-López, F. Javier Valverde-Muñoz, M. Carmen Muñoz, Maksym Seredyuk, José Antonio Real|2017|Inorg.Chem.|56|13535|doi:10.1021/acs.inorgchem.7b02272

research product

CCDC 1572182: Experimental Crystal Structure Determination

Related Article: Carlos Bartual-Murgui, Lucía Piñeiro-López, F. Javier Valverde-Muñoz, M. Carmen Muñoz, Maksym Seredyuk, José Antonio Real|2017|Inorg.Chem.|56|13535|doi:10.1021/acs.inorgchem.7b02272

research product

CCDC 1572179: Experimental Crystal Structure Determination

Related Article: Carlos Bartual-Murgui, Lucía Piñeiro-López, F. Javier Valverde-Muñoz, M. Carmen Muñoz, Maksym Seredyuk, José Antonio Real|2017|Inorg.Chem.|56|13535|doi:10.1021/acs.inorgchem.7b02272

research product

CCDC 1572178: Experimental Crystal Structure Determination

Related Article: Carlos Bartual-Murgui, Lucía Piñeiro-López, F. Javier Valverde-Muñoz, M. Carmen Muñoz, Maksym Seredyuk, José Antonio Real|2017|Inorg.Chem.|56|13535|doi:10.1021/acs.inorgchem.7b02272

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