0000000000294504

AUTHOR

Manuel Meneses-sánchez

showing 31 related works from this author

Enhanced Interplay between Host–Guest and Spin-Crossover Properties through the Introduction of an N Heteroatom in 2D Hofmann Clathrates

2021

Controlled modulation of the spin-crossover (SCO) behavior through the sorption-desorption of invited molecules is an extensively exploited topic because of its potential applications in molecular sensing. For this purpose, understanding the mechanisms by which the spin-switching properties are altered by guest molecules is of paramount importance. Here, we show an experimental approach revealing a direct probe of how the interplay between SCO and host-guest chemistry is noticeably activated by chemically tuning the host structure. Thus, the axial ligand 4-phenylpyridine (4-PhPy) in the 2D Hofmann clathrates {Fe(4-PhPy)2[M(CN)4]} (PhPyM; M = Pt, Pd) is replaced by 2,4-bipyridine (2,4-Bipy),…

010405 organic chemistryLigandHeteroatomSubstituent010402 general chemistry01 natural sciences0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundCrystallographyAdsorptionchemistrySpin crossoverMoleculeMethanolPhysical and Theoretical ChemistryChemical compositionInorganic Chemistry
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Bistable Hofmann-Type FeII Spin-Crossover Two-Dimensional Polymers of 4-Alkyldisulfanylpyridine for Prospective Grafting of Monolayers on Metallic Su…

2021

Aiming at investigating the suitability of Hofmann-type two-dimensional (2D) coordination polymers {FeII(Lax)2[MII(CN)4]} to be processed as single monolayers and probed as spin crossover (SCO) junctions in spintronic devices, the synthesis and characterization of the MII derivatives (MII = Pd and Pt) with sulfur-rich axial ligands (Lax = 4-methyl- and 4-ethyl-disulfanylpyridine) have been conducted. The thermal dependence of the magnetic and calorimetric properties confirmed the occurrence of strong cooperative SCO behavior in the temperature interval of 100-225 K, featuring hysteresis loops 44 and 32.5 K/21 K wide for PtII-methyl and PtII/PdII-ethyl derivatives, while the PdII-methyl deri…

chemistry.chemical_classificationSpintronics010405 organic chemistryChemistrymedia_common.quotation_subjectFrustrationPolymer010402 general chemistry01 natural sciences0104 chemical sciencesInorganic ChemistryMetalHysteresisCrystallographySpin crossovervisual_artExcited stateMonolayervisual_art.visual_art_mediumPhysical and Theoretical Chemistrymedia_commonInorganic Chemistry
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Discrimination between two memory channels by molecular alloying in a doubly bistable spin crossover material

2019

[EN] A multistable spin crossover (SCO) molecular alloy system [Fe1-xMx(nBu-im)(3)(tren)](P1-yAsyF6)(2) (M = Zn-II, Ni-II; (nBu-im)(3)(tren) = tris(n-butyl-imidazol(2-ethylamino))amine) has been synthesized and characterized. By controlling the composition of this isomorphous series, two cooperative thermally induced SCO events featuring distinct critical temperatures (T-c) and hysteresis widths (Delta T-c, memory) can be selected at will. The pristine derivative 100As (x = 0, y = 1) displays a strong cooperative two-step SCO and two reversible structural phase transitions (PTs). The low temperature PTLT and the SCO occur synchronously involving conformational changes of the ligand's n-buty…

Materials science010405 organic chemistryLigandHydrostatic pressureKineticsGeneral Chemistry010402 general chemistry01 natural sciences0104 chemical sciencesCrystallographyHysteresischemistry.chemical_compoundChemistrychemistrySpin crossoverIsomorphous substitutionFISICA APLICADASingle crystalDerivative (chemistry)Chemical Science
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Extrinsicvs.intrinsic luminescence and their interplay with spin crossover in 3D Hofmann-type coordination polymers

2020

The research of new multifunctional materials, as those undergoing spin crossover (SCO) and luminescent properties, is extremely important in the development of further optical and electronic switching devices. As a new step towards this ambitious aim, the coupling of SCO and fluorescence is presented here following two main strategies: whether the fluorescent agent is integrated as a part of the main structure of a 3D SCO coordination polymer {FeII(bpan)[MI(CN)2]2} (bpan = bis(4-pyridyl)anthracene, MI = Ag (FebpanAg), Au (FebpanAu)) or is a guest molecule inserted within the cavities of the 3D switchable framework {FeII(bpb)[MI(CN)2]2}·pyrene (bpb = bis(4-pyridyl)butadiyne, MI = Ag (FebpbA…

chemistry.chemical_classificationAnthraceneMaterials scienceCoordination polymer02 engineering and technologyGeneral ChemistryPolymer010402 general chemistry021001 nanoscience & nanotechnology01 natural sciencesFluorescence0104 chemical sciencesCrystallographychemistry.chemical_compoundchemistrySpin crossoverMaterials ChemistryMoleculeAbsorption (chemistry)0210 nano-technologyLuminescenceJournal of Materials Chemistry C
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Thermo- and photo-modulation of exciplex fluorescence in a 3D spin crossover Hofmann-type coordination polymer

2018

[EN] The search for bifunctional materials showing synergies between spin crossover (SCO) and luminescence has attracted substantial interest since they could be promising platforms for new switching electronic and optical technologies. In this context, we present the first three-dimensional Fe-II Hofmann-type coordination polymer exhibiting SCO properties and luminescence. The complex {Fe-II(bpben)[Au(CN)(2)]}@pyr (bpben = 1,4-bis(4-pyridyl)benzene) functionalized with pyrene (pyr) guests undergoes a cooperative multi-step SCO, which has been investigated by single crystal X-ray diffraction, single crystal UV-Vis absorption spectroscopy, and magnetic and calorimetric measurements. The resu…

Materials scienceAbsorption spectroscopyCoordination polymerPopulationContext (language use)02 engineering and technology010402 general chemistryPhotochemistry01 natural sciencesLIESSTEmissionchemistry.chemical_compoundComplexesSpin crossoverPressureeducationFE(ABPT)(2)(NCX)(2) XBehavioreducation.field_of_studyNanocompositeHysteresisGeneral Chemistry021001 nanoscience & nanotechnology0104 chemical sciencesChemistrychemistryFISICA APLICADATransitionNetworks0210 nano-technologyLuminescenceSingle crystalStateChemical Science
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Epitaxial Thin-Film vs Single Crystal Growth of 2D Hofmann-Type Iron(II) Materials: A Comparative Assessment of their Bi-Stable Spin Crossover Proper…

2020

Integration of the ON-OFF cooperative spin crossover (SCO) properties of FeII coordination polymers as components of electronic and/or spintronic devices is currently an area of great interest for potential applications. This requires the selection and growth of thin films of the appropriate material onto selected substrates. In this context, two new series of cooperative SCO two-dimensional FeII coordination polymers of the Hofmann-type formulated {FeII(Pym)2[MII(CN)4]·xH2O}n and {FeII(Isoq)2[MII(CN)4]}n (Pym = pyrimidine, Isoq = isoquinoline; MII = Ni, Pd, Pt) have been synthesized, characterized, and the corresponding Pt derivatives selected for fabrication of thin films by liquid-phase …

Materials scienceQuímica organometàl·lica010402 general chemistryEpitaxy01 natural sciencesHofmann-type clathratesspin crossoverSpin crossoverGeneral Materials ScienceHardware_ARITHMETICANDLOGICSTRUCTURESThin filmMaterialschemistry.chemical_classificationSpintronicsSingle crystal growth010405 organic chemistrybusiness.industryepitaxial growthEpitaxial thin filmPolymer0104 chemical sciencescoordination polymersBi stablesize-reduction effectchemistrythin filmsOptoelectronicsbusiness
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CCDC 1965274: Experimental Crystal Structure Determination

2020

Related Article: Manuel Meneses-Sánchez, Lucía Piñeiro-López, Teresa Delgado, Carlos Bartual-Murgui, M. Carmen Muñoz, Pradip Chakraborty, José Antonio Real|2020|J.Mater.Chem.C|8|1623|doi:10.1039/C9TC06422B

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-((mu-44'-(buta-13-diyne-14-diyl)dipyridine)-tetrakis(mu-cyano)-di-gold-iron pyrene)Experimental 3D Coordinates
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CCDC 1879899: Experimental Crystal Structure Determination

2019

Related Article: Francisco Javier Valverde-Muñoz, Maksym Seredyuk, Manuel Meneses-Sánchez, M. Carmen Muñoz, Carlos Bartual-Murgui, José A. Real|2019|Chemical Science|10|3807|doi:10.1039/C8SC05256E

Space GroupCrystallographyCrystal System(NNN-tris(2-(((1-n-butyl-1H-imidazol-2-yl)methylidene)amino)ethyl)amine)-iron bis(hexafluoroarsenate hexafluorophosphate)Crystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1879896: Experimental Crystal Structure Determination

2019

Related Article: Francisco Javier Valverde-Muñoz, Maksym Seredyuk, Manuel Meneses-Sánchez, M. Carmen Muñoz, Carlos Bartual-Murgui, José A. Real|2019|Chemical Science|10|3807|doi:10.1039/C8SC05256E

Space GroupCrystallography(NNN-tris(2-(((1-n-butyl-1H-imidazol-2-yl)methylidene)amino)ethyl)amine)-iron bis(hexafluoroarsenate)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1879901: Experimental Crystal Structure Determination

2019

Related Article: Francisco Javier Valverde-Muñoz, Maksym Seredyuk, Manuel Meneses-Sánchez, M. Carmen Muñoz, Carlos Bartual-Murgui, José A. Real|2019|Chemical Science|10|3807|doi:10.1039/C8SC05256E

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(NNN-tris(2-(((1-n-butyl-1H-imidazol-2-yl)methylidene)amino)ethyl)amine)-nickel bis(hexafluorophosphate)Experimental 3D Coordinates
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CCDC 1989161: Experimental Crystal Structure Determination

2020

Related Article: Carlos Bartual-Murgui, Víctor Rubio-Giménez, Manuel Meneses-Sánchez, Francisco Javier Valverde-Muñoz, Sergio Tatay, Carlos Martí-Gastaldo, M. Carmen Muñoz, José Antonio Real|2020|ACS Applied Materials and Interfaces|12|29461|doi:10.1021/acsami.0c05733

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-(tetrakis(mu-cyano)-bis(isoquinoline)-iron-palladium)Experimental 3D Coordinates
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CCDC 1989160: Experimental Crystal Structure Determination

2020

Related Article: Carlos Bartual-Murgui, Víctor Rubio-Giménez, Manuel Meneses-Sánchez, Francisco Javier Valverde-Muñoz, Sergio Tatay, Carlos Martí-Gastaldo, M. Carmen Muñoz, José Antonio Real|2020|ACS Applied Materials and Interfaces|12|29461|doi:10.1021/acsami.0c05733

Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinatescatena-(tetrakis(mu-cyano)-bis(isoquinoline)-iron-nickel)
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CCDC 1989157: Experimental Crystal Structure Determination

2020

Related Article: Carlos Bartual-Murgui, Víctor Rubio-Giménez, Manuel Meneses-Sánchez, Francisco Javier Valverde-Muñoz, Sergio Tatay, Carlos Martí-Gastaldo, M. Carmen Muñoz, José Antonio Real|2020|ACS Applied Materials and Interfaces|12|29461|doi:10.1021/acsami.0c05733

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-(tetrakis(mu-cyano)-bis(pyrimidine)-iron-palladium monohydrate)Experimental 3D Coordinates
researchProduct

CCDC 1847351: Experimental Crystal Structure Determination

2018

Related Article: Teresa Delgado, Manuel Meneses-Sánchez, Lucía Piñeiro-López, Carlos Bartual-Murgui, M. Carmen Muñoz, José Antonio Real|2018|Chemical Science|9|8446|doi:10.1039/C8SC02677G

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[bis(mu-44'-(14-phenylene)dipyridine)-octakis(mu-cyano)-tetra-gold-di-iron bis(pyrene)]Experimental 3D Coordinates
researchProduct

CCDC 1910990: Experimental Crystal Structure Determination

2020

Related Article: Carlos Bartual-Murgui, Víctor Rubio-Giménez, Manuel Meneses-Sánchez, Francisco Javier Valverde-Muñoz, Sergio Tatay, Carlos Martí-Gastaldo, M. Carmen Muñoz, José Antonio Real|2020|ACS Applied Materials and Interfaces|12|29461|doi:10.1021/acsami.0c05733

catena-(tetrakis(mu-cyano)-bis(isoquinoline)-iron-platinum)Space GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1879898: Experimental Crystal Structure Determination

2019

Related Article: Francisco Javier Valverde-Muñoz, Maksym Seredyuk, Manuel Meneses-Sánchez, M. Carmen Muñoz, Carlos Bartual-Murgui, José A. Real|2019|Chemical Science|10|3807|doi:10.1039/C8SC05256E

Space GroupCrystallographyCrystal System(NNN-tris(2-(((1-n-butyl-1H-imidazol-2-yl)methylidene)amino)ethyl)amine)-iron bis(hexafluoroarsenate hexafluorophosphate)Crystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1847352: Experimental Crystal Structure Determination

2018

Related Article: Teresa Delgado, Manuel Meneses-Sánchez, Lucía Piñeiro-López, Carlos Bartual-Murgui, M. Carmen Muñoz, José Antonio Real|2018|Chemical Science|9|8446|doi:10.1039/C8SC02677G

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-[bis(mu-44'-(14-phenylene)dipyridine)-octakis(mu-cyano)-tetra-gold-di-iron bis(pyrene)]Experimental 3D Coordinates
researchProduct

CCDC 1989159: Experimental Crystal Structure Determination

2020

Related Article: Carlos Bartual-Murgui, Víctor Rubio-Giménez, Manuel Meneses-Sánchez, Francisco Javier Valverde-Muñoz, Sergio Tatay, Carlos Martí-Gastaldo, M. Carmen Muñoz, José Antonio Real|2020|ACS Applied Materials and Interfaces|12|29461|doi:10.1021/acsami.0c05733

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-(tetrakis(mu-cyano)-(mu-pyrimidine)-(pyrimidine)-iron-nickel)Experimental 3D Coordinates
researchProduct

CCDC 1910992: Experimental Crystal Structure Determination

2020

Related Article: Carlos Bartual-Murgui, Víctor Rubio-Giménez, Manuel Meneses-Sánchez, Francisco Javier Valverde-Muñoz, Sergio Tatay, Carlos Martí-Gastaldo, M. Carmen Muñoz, José Antonio Real|2020|ACS Applied Materials and Interfaces|12|29461|doi:10.1021/acsami.0c05733

Space GroupCrystallographycatena-(tetrakis(mu-cyano)-bis(pyrimidine)-iron-platinum hemihydrate)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1879900: Experimental Crystal Structure Determination

2019

Related Article: Francisco Javier Valverde-Muñoz, Maksym Seredyuk, Manuel Meneses-Sánchez, M. Carmen Muñoz, Carlos Bartual-Murgui, José A. Real|2019|Chemical Science|10|3807|doi:10.1039/C8SC05256E

Space GroupCrystallographyCrystal System(NNN-tris(2-(((1-n-butyl-1H-imidazol-2-yl)methylidene)amino)ethyl)amine)-iron bis(hexafluoroarsenate hexafluorophosphate)Crystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1965275: Experimental Crystal Structure Determination

2020

Related Article: Manuel Meneses-Sánchez, Lucía Piñeiro-López, Teresa Delgado, Carlos Bartual-Murgui, M. Carmen Muñoz, Pradip Chakraborty, José Antonio Real|2020|J.Mater.Chem.C|8|1623|doi:10.1039/C9TC06422B

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-((mu-44'-(buta-13-diyne-14-diyl)dipyridine)-tetrakis(mu-cyano)-iron-di-silver pyrene)Experimental 3D Coordinates
researchProduct

CCDC 1965272: Experimental Crystal Structure Determination

2020

Related Article: Manuel Meneses-Sánchez, Lucía Piñeiro-López, Teresa Delgado, Carlos Bartual-Murgui, M. Carmen Muñoz, Pradip Chakraborty, José Antonio Real|2020|J.Mater.Chem.C|8|1623|doi:10.1039/C9TC06422B

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-((mu-44'-(anthracene-910-diyl)dipyridine)-tetrakis(mu-cyano)-di-gold-iron)Experimental 3D Coordinates
researchProduct

CCDC 1965273: Experimental Crystal Structure Determination

2020

Related Article: Manuel Meneses-Sánchez, Lucía Piñeiro-López, Teresa Delgado, Carlos Bartual-Murgui, M. Carmen Muñoz, Pradip Chakraborty, José Antonio Real|2020|J.Mater.Chem.C|8|1623|doi:10.1039/C9TC06422B

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-((mu-44'-(buta-13-diyne-14-diyl)dipyridine)-tetrakis(mu-cyano)-iron-di-silver pyrene)Experimental 3D Coordinates
researchProduct

CCDC 1892385: Experimental Crystal Structure Determination

2019

Related Article: Francisco Javier Valverde-Muñoz, Maksym Seredyuk, Manuel Meneses-Sánchez, M. Carmen Muñoz, Carlos Bartual-Murgui, José A. Real|2019|Chemical Science|10|3807|doi:10.1039/C8SC05256E

Space GroupCrystallographyCrystal SystemCrystal Structure(NNN-tris(2-(((1-n-butyl-1H-imidazol-2-yl)methylidene)amino)ethyl)amine)-iron bis(hexafluorophosphate)Cell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1965271: Experimental Crystal Structure Determination

2020

Related Article: Manuel Meneses-Sánchez, Lucía Piñeiro-López, Teresa Delgado, Carlos Bartual-Murgui, M. Carmen Muñoz, Pradip Chakraborty, José Antonio Real|2020|J.Mater.Chem.C|8|1623|doi:10.1039/C9TC06422B

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-((mu-44'-(anthracene-910-diyl)dipyridine)-tetrakis(mu-cyano)-di-gold-iron)Experimental 3D Coordinates
researchProduct

CCDC 1989162: Experimental Crystal Structure Determination

2020

Related Article: Carlos Bartual-Murgui, Víctor Rubio-Giménez, Manuel Meneses-Sánchez, Francisco Javier Valverde-Muñoz, Sergio Tatay, Carlos Martí-Gastaldo, M. Carmen Muñoz, José Antonio Real|2020|ACS Applied Materials and Interfaces|12|29461|doi:10.1021/acsami.0c05733

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-(tetrakis(mu-cyano)-bis(isoquinoline)-iron-palladium)Experimental 3D Coordinates
researchProduct

CCDC 1965270: Experimental Crystal Structure Determination

2020

Related Article: Manuel Meneses-Sánchez, Lucía Piñeiro-López, Teresa Delgado, Carlos Bartual-Murgui, M. Carmen Muñoz, Pradip Chakraborty, José Antonio Real|2020|J.Mater.Chem.C|8|1623|doi:10.1039/C9TC06422B

Space GroupCrystallographyCrystal Systemcatena-(bis(mu-44'-(anthracene-910-diyl)dipyridine)-octakis(mu-cyano)-di-iron-tetra-gold)Crystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1862017: Experimental Crystal Structure Determination

2018

Related Article: Teresa Delgado, Manuel Meneses-Sánchez, Lucía Piñeiro-López, Carlos Bartual-Murgui, M. Carmen Muñoz, José Antonio Real|2018|Chemical Science|9|8446|doi:10.1039/C8SC02677G

Space GroupCrystallographyCrystal Systemcatena-[bis(mu-44'-(14-phenylene)dipyridine)-octakis(mu-cyano)-tetra-gold-di-zinc bis(pyrene)]Crystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1989158: Experimental Crystal Structure Determination

2020

Related Article: Carlos Bartual-Murgui, Víctor Rubio-Giménez, Manuel Meneses-Sánchez, Francisco Javier Valverde-Muñoz, Sergio Tatay, Carlos Martí-Gastaldo, M. Carmen Muñoz, José Antonio Real|2020|ACS Applied Materials and Interfaces|12|29461|doi:10.1021/acsami.0c05733

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterscatena-(tetrakis(mu-cyano)-bis(pyrimidine)-iron-palladium monohydrate)Experimental 3D Coordinates
researchProduct

CCDC 1847353: Experimental Crystal Structure Determination

2018

Related Article: Teresa Delgado, Manuel Meneses-Sánchez, Lucía Piñeiro-López, Carlos Bartual-Murgui, M. Carmen Muñoz, José Antonio Real|2018|Chemical Science|9|8446|doi:10.1039/C8SC02677G

Space GroupCrystallographyCrystal Systemcatena-[bis(mu-44'-(14-phenylene)dipyridine)-octakis(mu-cyano)-tetra-gold-di-zinc bis(pyrene)]Crystal StructureCell ParametersExperimental 3D Coordinates
researchProduct

CCDC 1879897: Experimental Crystal Structure Determination

2019

Related Article: Francisco Javier Valverde-Muñoz, Maksym Seredyuk, Manuel Meneses-Sánchez, M. Carmen Muñoz, Carlos Bartual-Murgui, José A. Real|2019|Chemical Science|10|3807|doi:10.1039/C8SC05256E

Space GroupCrystallography(NNN-tris(2-(((1-n-butyl-1H-imidazol-2-yl)methylidene)amino)ethyl)amine)-iron bis(hexafluoroarsenate)Crystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
researchProduct