0000000000296575
AUTHOR
Pierre Bertrand
Libellus de iurisdictione ecclesiastica contra Petrum de Cugneriis
L. gòt. i rom. - 3 tam. - 2 col. - 45 lín. - Esp. o min. p. inic. - Esc. tip.
Structural Stability of Hafnia-Based Materials at Ultra-High Temperature
This study assesses the structural stability at ultra-high temperature of the following selected compositions: 6.5 and 14 mol. % of RE2O3 (RE = Dy, Y, Er, Yb, and Lu) doped HfO2. Under thermal cycling and thermal shock, the structural stability was evaluated at 2400°C with water vapor flux using a specific test bench with a 3 kW CO2 laser. The cubic phase stability, which is theoretically important in the broad temperature range from 25 to 2800°C, was determined by a quantitative analysis of the X-ray diffractograms. Fully and partially stabilized HfO2, obtained respectively with 14 mol. % and 6.5 mol. % of dopants, showed different behaviors to thermal damage. Thermal expansion was measure…
Manufacturing and testing of a metal supported Ni-YSZ/YSZ/La2NiO4 IT-SOFC synthesized by physical surface deposition processes
International audience; The manufacture of the last generation metal supported IT-SOFC complete cell by dry surface deposition pro-cesses is really challenging. Atmospheric Plasma Spraying (APS) and Reactive Magnetron Sputtering (RMS) processes are respectively adapted to deposit Ni-YSZ anode and YSZ electrolyte layers. RMS is also used to coat a thin and dense La2NiO4 (LNO) cathode layer. In this work, we have realized a complete cell on metallic support (ITM) produced by PLANSEE SE. The innovative LNO cathode layer was compared with screen-printed LNO layers, with and without RMS bonding layer. Electrochemical and Voltammetry tests were performed on these samples. It reveals lower perform…