0000000000296657
AUTHOR
M. Stella Colomba
Organometallic Complexes with Biological Molecules: VIII. Synthesis, Solid State andin vivo Investigation of Triorganotin(IV) Derivatives ofL-Homocysteic Acid
Several new triorganotin(IV) derivatives of L-homocysteic acid (L-HCAH) with formula R3Sn(L-HCA) (R=Me, nBu, Ph) have been synthesized. Their solid-state configurations were determined by IR and Mossbauer spectroscopy. The tin(IV) atom is five-coordinated in all the complexes, with the L-homocysteic acid behaving as a monoanionic bidentate ligand coordinating the tin(IV) atom through a chelating or bridging carboxylate group. The sulfonate (SO3−) and NH3+ groups of L-homocysteic acid maintain their free acid configuration and hence do not participate to the coordination of the tin(IV) atom. Coordination hypotheses have been checked through the correlation between the Mossbauer parameter iso…
Qanat, gebbie and water sources: the last refuge for the malacologican freshwater fauna in Palermo (Sicily, Italy)
The surroundings of Palermo were characterized, over the centuries, by the presence of many natural environments of great ecological and faunal importance. These environments were placed in a context characterized by minimal and sustainable urban development and large agriculture areas, dedicated to the development of tree crops such as citrus and orchards. These crops were supported by an imposing irrigation system that, using natural resources such as watercourses, wells and springs, collected and distributed water in soils through tanks, gebbie, qanat, irrigation channels (saje), etc. Fresh water mollusks, like many other animal and vegetable organisms, spread from the natural freshwater…