0000000000301385
AUTHOR
Alexandra M. Z. Slawin
Original packing and unusual molecular conformation of the bis(ethylenedithio)tetrathiafulvalene (ET) donors induced by cation–anion interactions in the radical salt ET5[B10I10]·(CH2Cl2)0.8
The crystal structure of the radical salt ET5[B10I10]·0.8CH2Cl2 has been determined and the packing and molecular conformation of the organic donors are discussed in terms of the C–H⋯I contacts between the ethylene groups of the ET molecules and the iodine atoms of the borane anion [B10I10]2−.
Green phosphorescence and electroluminescence of sulfur pentafluoride-functionalized cationic iridium(III) complexes
EZ-C acknowledges the University of St Andrews for financial support. We report four cationic iridium(III) complexes [Ir(C^N)2(dtBubpy)](PF6) that have sulfurpentafluoride-modified 1-phenylpyrazole and 2-phenylpyridine cyclometalating (C^N) ligands (dtBubpy = 4,4'-di-tert-butyl-2,2'-bipyridyl). Three of the complexes were characterized by single-crystal X-ray structure analysis. In cyclic voltammetry, the complexes undergo reversible oxidation of iridium(III) and irreversible reduction of the SF5 group. They emit bright green phosphorescence in acetonitrile solution and in thin films at room temperature, with emission maxima between 482–519 nm and photoluminescence quantum yields of up to 7…
Synthesis, Structure and Antimicrobial Activity of New Co(II) Complex with bis-Morpholino/Benzoimidazole-s-Triazine Ligand
A new Co(II) perchlorate complex of the bis-morpholino/benzoimidazole-s-triazine ligand, 4,4′-(6-(1H-benzo[d]imidazol-1-yl)-1,3,5-triazine-2,4-diyl)dimorpholine (BMBIT), was synthesized and characterized. The structure of the new Co(II) complex was approved to be [Co(BMBIT)2(H2O)4](ClO4)2*H2O using single-crystal X-ray diffraction. The Co(II) complex was found crystallized in the monoclinic crystal system and P21/c space group. The unit cell parameters are a = 22.21971(11) Å, b = 8.86743(4) Å, c = 24.38673(12) Å and β = 113.4401(6)°. This heteroleptic complex has distorted octahedral coordination geometry with two monodenatate BMBIT ligand units via the benzoimidazole N-atom and four water …
Wide-Bite-Angle Diphosphine Ligands in Thermally Activated Delayed Fluorescent Copper(I) Complexes: Impact on the Performance of Electroluminescence Applications.
We report a series of seven cationic heteroleptic copper(I) complexes of the form [Cu(P^P)(dmphen)]BF4, where dmphen is 2,9-dimethyl-1,10-phenanthroline and P^P is a diphosphine chelate, in which the effect of the bite angle of the diphosphine ligand on the photophysical properties of the complexes was studied. Several of the complexes exhibit moderately high photoluminescence quantum yields in the solid state, with ΦPL of up to 35%, and in solution, with ΦPL of up to 98%. We were able to correlate the powder photoluminescence quantum yields with the % Vbur of the P^P ligand. The most emissive complexes were used to fabricate both organic light-emitting diodes and light-emitting electrochem…
Isolation of Four New CoII/CoIII and NiII Complexes with a Pentadentate Schiff Base Ligand: Syntheses, Structural Descriptions and Magnetic Studies
In this paper we report the temperature and pH dependent syntheses and systematic characterization of four new Co(II)/Co(III) and Ni(II) complexes with a pentadentate Schiff base ligand H(3)L obtained by condensing 1,3,-diaminopropan-2-ol with 2-hydroxyacetophenone in 1:2 molar ratio. The room temperature syntheses involving Co(II) and Ni(II) nitrates and the ligand H(3)L lead to the isolation of the dinuclear species [Co(2)L(2)(H(2)O)] (1), and the mononuclear complex [Ni(LH)] (3), respectively, whereas refluxing at basic pH leads to the tetranuclear complexes, [Co(II)(2)Co(III)(2)L(2)(μ(3)-OMe)(2)(NO(3))(H(2)O)(2)]NO(3)·2(H(2)O) (2), and [Ni(4)L(2)(μ(3)-OMe)(2)(H(2)O)(2)]·2H(2)O (4). 1 is…
Crystallisation of H3BTC, H3TPO or H2SDA with MII (M = Co, Mn or Zn) and 2,2′-bipyridyl: design and control of co-ordination architecture, and magnetic properties (H3BTC = benzene-1,3,5-tricarboxylic acid, H3TPO = tris(4-carboxylphenyl)phosphine oxide, H2SDA = cis-stilbene-4,4′-dicarboxylic acid) †
The hydrothermal reaction of benzene-1,3,5-tricarboxylic acid (H3BTC) with MII (M = Mn, Co or Zn), tris(4-carboxyphenyl)phosphine oxide (H3TPO) or cis-stilbene-4,4′-dicarboxylic acid (H2SDA) with CoII and 2,2′-bipyridyl (BIPY) gave 1-D co-ordination networks formulated as: [M(HBTC)(BIPY)(H2O)] (M = Mn 1, Co 2, or Zn 3; [Co3(BTC)2(BIPY)2(H2O)6]·4H2O 4, [Co3(TPO)2(BIPY)2(H2O)6]·xH2O 5 and [Co(SDA)(BIPY)(H2O)] 6. Structures 1 and 2 consist of double stranded chains of alternating HBTC dianions and dimeric units MII–MII linked by two µ-(1,1) bridging carboxylates. Magnetic properties of 1 and 2 indicate the presence of ferromagnetic exchange interactions within the dimers. Structures 4 and 5 co…
Synthesis, characterization, X-ray crystallography, and antimicrobial activities of Ni(II) and Cu(II) complexes with a salicylaldehyde-based thiosemicarbazone ligand
A new salicylaldehyde-based ‘ONS’ tridentate salicylaldehyde-N(4)-diethylthiosemicarbazone (H2SANEt2) has been synthesized and characterized by elemental analyses, mass, IR, and 1H NMR spectral parameters. The coordination mode of the synthesized ligand is reported by solid state isolation and physico-chemical identification of Ni(II) and Cu(II) complexes, [Ni(SANEt2)]2 (1) and [Cu(SANEt2)]2 (2). Both complexes are neutral and oxygen-bridged dinuclear species. The ligand is bideprotonated ‘ONS’ tridentate in both complexes. IR spectral data indicate that coordination of each metal of the two complexes occurs through phenolic oxygen, azomethine nitrogen, and thiolato sulfur. X-ray crystallog…
Enhancing the photoluminescence quantum yields of blue-emitting cationic iridium(iii) complexes bearing bisphosphine ligands
EZ-C acknowledges the University of St Andrews for financial support. We thank Johnson Matthey and Umicore AG for the gift of materials and Cihang Yu for the preparation of isopropxantphos. We thank Dr. Nail Shaveleev for the synthesis of NMS25. IDWS and AKB acknowledge support from EPSRC (EP/J01771X). This work has been supported by the Spanish Ministry of Economy and Competitiveness (MINECO) MAT2014-55200. Herein we present a structure-property relationship study of thirteen cationic iridium (III) complexes of the form of [Ir(C^N)2(P^P)]PF6 in both solution and the solid state through systematic evaluation of six bisphosphine (P^P) ligands (xantphos, dpephos, dppe, Dppe, nixantphos and is…
CCDC 1490702: Experimental Crystal Structure Determination
Related Article: Diego Rota Martir, Cristina Momblona, Antonio Pertegás, David B. Cordes, Alexandra M. Z. Slawin, Henk J. Bolink, and Eli Zysman-Colman|2016|ACS Applied Materials and Interfaces|8|33907|doi:10.1021/acsami.6b14050
CCDC 1423252: Experimental Crystal Structure Determination
Related Article: Diego Rota Martir, Ashu K. Bansal, Vincent Di Mascio, David B. Cordes, Adam F. Henwood, Alexandra M. Z. Slawin, Paul C. J. Kamer, Laura Martínez-Sarti, Antonio Pertegás, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2016|Inorg.Chem.Front.|3|218|doi:10.1039/C5QI00177C
CCDC 1546695: Experimental Crystal Structure Determination
Related Article: Adam F. Henwood, Amlan K. Pal, David B. Cordes, Alexandra M. Z. Slawin, Thomas W. Rees, Cristina Momblona, Azin Babaei, Antonio Pertegás, Enrique Ortí, Henk J. Bolink, Etienne Baranoff, Eli Zysman-Colman|2017|J.Mater.Chem.C|5|9638|doi:10.1039/C7TC03110F
CCDC 1490703: Experimental Crystal Structure Determination
Related Article: Diego Rota Martir, Cristina Momblona, Antonio Pertegás, David B. Cordes, Alexandra M. Z. Slawin, Henk J. Bolink, and Eli Zysman-Colman|2016|ACS Applied Materials and Interfaces|8|33907|doi:10.1021/acsami.6b14050
CCDC 1423251: Experimental Crystal Structure Determination
Related Article: Diego Rota Martir, Ashu K. Bansal, Vincent Di Mascio, David B. Cordes, Adam F. Henwood, Alexandra M. Z. Slawin, Paul C. J. Kamer, Laura Martínez-Sarti, Antonio Pertegás, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2016|Inorg.Chem.Front.|3|218|doi:10.1039/C5QI00177C
CCDC 2061123: Experimental Crystal Structure Determination
Related Article: Chenfei Li, Campbell F. R. Mackenzie, Said A. Said, Amlan K. Pal, Mohammad A. Haghighatbin, Azin Babaei, Michele Sessolo, David B. Cordes, Alexandra M. Z. Slawin, Paul C. J. Kamer, Henk J. Bolink, Conor F. Hogan, Eli Zysman-Colman|2021|Inorg.Chem.|60|10323|doi:10.1021/acs.inorgchem.1c00804
CCDC 1490707: Experimental Crystal Structure Determination
Related Article: Diego Rota Martir, Cristina Momblona, Antonio Pertegás, David B. Cordes, Alexandra M. Z. Slawin, Henk J. Bolink, and Eli Zysman-Colman|2016|ACS Applied Materials and Interfaces|8|33907|doi:10.1021/acsami.6b14050
CCDC 1546696: Experimental Crystal Structure Determination
Related Article: Adam F. Henwood, Amlan K. Pal, David B. Cordes, Alexandra M. Z. Slawin, Thomas W. Rees, Cristina Momblona, Azin Babaei, Antonio Pertegás, Enrique Ortí, Henk J. Bolink, Etienne Baranoff, Eli Zysman-Colman|2017|J.Mater.Chem.C|5|9638|doi:10.1039/C7TC03110F
CCDC 1423253: Experimental Crystal Structure Determination
Related Article: Diego Rota Martir, Ashu K. Bansal, Vincent Di Mascio, David B. Cordes, Adam F. Henwood, Alexandra M. Z. Slawin, Paul C. J. Kamer, Laura Martínez-Sarti, Antonio Pertegás, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2016|Inorg.Chem.Front.|3|218|doi:10.1039/C5QI00177C
CCDC 2061124: Experimental Crystal Structure Determination
Related Article: Chenfei Li, Campbell F. R. Mackenzie, Said A. Said, Amlan K. Pal, Mohammad A. Haghighatbin, Azin Babaei, Michele Sessolo, David B. Cordes, Alexandra M. Z. Slawin, Paul C. J. Kamer, Henk J. Bolink, Conor F. Hogan, Eli Zysman-Colman|2021|Inorg.Chem.|60|10323|doi:10.1021/acs.inorgchem.1c00804
CCDC 2061121: Experimental Crystal Structure Determination
Related Article: Chenfei Li, Campbell F. R. Mackenzie, Said A. Said, Amlan K. Pal, Mohammad A. Haghighatbin, Azin Babaei, Michele Sessolo, David B. Cordes, Alexandra M. Z. Slawin, Paul C. J. Kamer, Henk J. Bolink, Conor F. Hogan, Eli Zysman-Colman|2021|Inorg.Chem.|60|10323|doi:10.1021/acs.inorgchem.1c00804
CCDC 1053872: Experimental Crystal Structure Determination
Related Article: Nail M. Shavaleev, Guohua Xie, Shinto Varghese, David B. Cordes, Alexandra M. Z. Slawin, Cristina Momblona, Enrique Ortí, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2015|Inorg.Chem.|54|5907|doi:10.1021/acs.inorgchem.5b00717
CCDC 1053870: Experimental Crystal Structure Determination
Related Article: Nail M. Shavaleev, Guohua Xie, Shinto Varghese, David B. Cordes, Alexandra M. Z. Slawin, Cristina Momblona, Enrique Ortí, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2015|Inorg.Chem.|54|5907|doi:10.1021/acs.inorgchem.5b00717
CCDC 2061118: Experimental Crystal Structure Determination
Related Article: Chenfei Li, Campbell F. R. Mackenzie, Said A. Said, Amlan K. Pal, Mohammad A. Haghighatbin, Azin Babaei, Michele Sessolo, David B. Cordes, Alexandra M. Z. Slawin, Paul C. J. Kamer, Henk J. Bolink, Conor F. Hogan, Eli Zysman-Colman|2021|Inorg.Chem.|60|10323|doi:10.1021/acs.inorgchem.1c00804
CCDC 1423259: Experimental Crystal Structure Determination
Related Article: Diego Rota Martir, Ashu K. Bansal, Vincent Di Mascio, David B. Cordes, Adam F. Henwood, Alexandra M. Z. Slawin, Paul C. J. Kamer, Laura Martínez-Sarti, Antonio Pertegás, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2016|Inorg.Chem.Front.|3|218|doi:10.1039/C5QI00177C
CCDC 2061119: Experimental Crystal Structure Determination
Related Article: Chenfei Li, Campbell F. R. Mackenzie, Said A. Said, Amlan K. Pal, Mohammad A. Haghighatbin, Azin Babaei, Michele Sessolo, David B. Cordes, Alexandra M. Z. Slawin, Paul C. J. Kamer, Henk J. Bolink, Conor F. Hogan, Eli Zysman-Colman|2021|Inorg.Chem.|60|10323|doi:10.1021/acs.inorgchem.1c00804
CCDC 1490708: Experimental Crystal Structure Determination
Related Article: Diego Rota Martir, Cristina Momblona, Antonio Pertegás, David B. Cordes, Alexandra M. Z. Slawin, Henk J. Bolink, and Eli Zysman-Colman|2016|ACS Applied Materials and Interfaces|8|33907|doi:10.1021/acsami.6b14050
CCDC 1490705: Experimental Crystal Structure Determination
Related Article: Diego Rota Martir, Cristina Momblona, Antonio Pertegás, David B. Cordes, Alexandra M. Z. Slawin, Henk J. Bolink, and Eli Zysman-Colman|2016|ACS Applied Materials and Interfaces|8|33907|doi:10.1021/acsami.6b14050
CCDC 1546698: Experimental Crystal Structure Determination
Related Article: Adam F. Henwood, Amlan K. Pal, David B. Cordes, Alexandra M. Z. Slawin, Thomas W. Rees, Cristina Momblona, Azin Babaei, Antonio Pertegás, Enrique Ortí, Henk J. Bolink, Etienne Baranoff, Eli Zysman-Colman|2017|J.Mater.Chem.C|5|9638|doi:10.1039/C7TC03110F
CCDC 1490429: Experimental Crystal Structure Determination
Related Article: Amlan K. Pal, David B. Cordes, Alexandra M. Z. Slawin, Cristina Momblona, Enrique Ortı́, Ifor D. W. Samuel, Henk J. Bolink, and Eli Zysman-Colman|2016|Inorg.Chem.|55|10361|doi:10.1021/acs.inorgchem.6b01602
CCDC 1423255: Experimental Crystal Structure Determination
Related Article: Diego Rota Martir, Ashu K. Bansal, Vincent Di Mascio, David B. Cordes, Adam F. Henwood, Alexandra M. Z. Slawin, Paul C. J. Kamer, Laura Martínez-Sarti, Antonio Pertegás, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2016|Inorg.Chem.Front.|3|218|doi:10.1039/C5QI00177C
CCDC 1538393: Experimental Crystal Structure Determination
Related Article: Amlan K. Pal, David B. Cordes, Alexandra M. Z. Slawin, Cristina Momblona, Antonio Pertegás, Enrique Ortí, Henk J. Bolink, Eli Zysman-Colman|2017|RSC Advances|7|31833|doi:10.1039/C7RA06347D
CCDC 1538394: Experimental Crystal Structure Determination
Related Article: Amlan K. Pal, David B. Cordes, Alexandra M. Z. Slawin, Cristina Momblona, Antonio Pertegás, Enrique Ortí, Henk J. Bolink, Eli Zysman-Colman|2017|RSC Advances|7|31833|doi:10.1039/C7RA06347D
CCDC 1423254: Experimental Crystal Structure Determination
Related Article: Diego Rota Martir, Ashu K. Bansal, Vincent Di Mascio, David B. Cordes, Adam F. Henwood, Alexandra M. Z. Slawin, Paul C. J. Kamer, Laura Martínez-Sarti, Antonio Pertegás, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2016|Inorg.Chem.Front.|3|218|doi:10.1039/C5QI00177C
CCDC 2061120: Experimental Crystal Structure Determination
Related Article: Chenfei Li, Campbell F. R. Mackenzie, Said A. Said, Amlan K. Pal, Mohammad A. Haghighatbin, Azin Babaei, Michele Sessolo, David B. Cordes, Alexandra M. Z. Slawin, Paul C. J. Kamer, Henk J. Bolink, Conor F. Hogan, Eli Zysman-Colman|2021|Inorg.Chem.|60|10323|doi:10.1021/acs.inorgchem.1c00804
CCDC 1490428: Experimental Crystal Structure Determination
Related Article: Amlan K. Pal, David B. Cordes, Alexandra M. Z. Slawin, Cristina Momblona, Enrique Ortı́, Ifor D. W. Samuel, Henk J. Bolink, and Eli Zysman-Colman|2016|Inorg.Chem.|55|10361|doi:10.1021/acs.inorgchem.6b01602
CCDC 1546697: Experimental Crystal Structure Determination
Related Article: Adam F. Henwood, Amlan K. Pal, David B. Cordes, Alexandra M. Z. Slawin, Thomas W. Rees, Cristina Momblona, Azin Babaei, Antonio Pertegás, Enrique Ortí, Henk J. Bolink, Etienne Baranoff, Eli Zysman-Colman|2017|J.Mater.Chem.C|5|9638|doi:10.1039/C7TC03110F
CCDC 2061122: Experimental Crystal Structure Determination
Related Article: Chenfei Li, Campbell F. R. Mackenzie, Said A. Said, Amlan K. Pal, Mohammad A. Haghighatbin, Azin Babaei, Michele Sessolo, David B. Cordes, Alexandra M. Z. Slawin, Paul C. J. Kamer, Henk J. Bolink, Conor F. Hogan, Eli Zysman-Colman|2021|Inorg.Chem.|60|10323|doi:10.1021/acs.inorgchem.1c00804
CCDC 1423258: Experimental Crystal Structure Determination
Related Article: Diego Rota Martir, Ashu K. Bansal, Vincent Di Mascio, David B. Cordes, Adam F. Henwood, Alexandra M. Z. Slawin, Paul C. J. Kamer, Laura Martínez-Sarti, Antonio Pertegás, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2016|Inorg.Chem.Front.|3|218|doi:10.1039/C5QI00177C
CCDC 1490430: Experimental Crystal Structure Determination
Related Article: Amlan K. Pal, David B. Cordes, Alexandra M. Z. Slawin, Cristina Momblona, Enrique Ortı́, Ifor D. W. Samuel, Henk J. Bolink, and Eli Zysman-Colman|2016|Inorg.Chem.|55|10361|doi:10.1021/acs.inorgchem.6b01602
CCDC 1423257: Experimental Crystal Structure Determination
Related Article: Diego Rota Martir, Ashu K. Bansal, Vincent Di Mascio, David B. Cordes, Adam F. Henwood, Alexandra M. Z. Slawin, Paul C. J. Kamer, Laura Martínez-Sarti, Antonio Pertegás, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2016|Inorg.Chem.Front.|3|218|doi:10.1039/C5QI00177C
CCDC 1490706: Experimental Crystal Structure Determination
Related Article: Diego Rota Martir, Cristina Momblona, Antonio Pertegás, David B. Cordes, Alexandra M. Z. Slawin, Henk J. Bolink, and Eli Zysman-Colman|2016|ACS Applied Materials and Interfaces|8|33907|doi:10.1021/acsami.6b14050
CCDC 1490704: Experimental Crystal Structure Determination
Related Article: Diego Rota Martir, Cristina Momblona, Antonio Pertegás, David B. Cordes, Alexandra M. Z. Slawin, Henk J. Bolink, and Eli Zysman-Colman|2016|ACS Applied Materials and Interfaces|8|33907|doi:10.1021/acsami.6b14050
CCDC 1053871: Experimental Crystal Structure Determination
Related Article: Nail M. Shavaleev, Guohua Xie, Shinto Varghese, David B. Cordes, Alexandra M. Z. Slawin, Cristina Momblona, Enrique Ortí, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2015|Inorg.Chem.|54|5907|doi:10.1021/acs.inorgchem.5b00717
CCDC 1423256: Experimental Crystal Structure Determination
Related Article: Diego Rota Martir, Ashu K. Bansal, Vincent Di Mascio, David B. Cordes, Adam F. Henwood, Alexandra M. Z. Slawin, Paul C. J. Kamer, Laura Martínez-Sarti, Antonio Pertegás, Henk J. Bolink, Ifor D. W. Samuel, Eli Zysman-Colman|2016|Inorg.Chem.Front.|3|218|doi:10.1039/C5QI00177C
CCDC 1490431: Experimental Crystal Structure Determination
Related Article: Amlan K. Pal, David B. Cordes, Alexandra M. Z. Slawin, Cristina Momblona, Enrique Ortı́, Ifor D. W. Samuel, Henk J. Bolink, and Eli Zysman-Colman|2016|Inorg.Chem.|55|10361|doi:10.1021/acs.inorgchem.6b01602