0000000000308854

AUTHOR

Rosina Rainieri

showing 4 related works from this author

Synthesis and spectroscopic characterizations of both 1-ethyl-4,8-dihydro-10-methoxy-3-methyl-8-r1-6-r2-dipyrazolo[3,4-b:4′,3′-f]-[1,5]diazocin-5(1H)…

1995

The non-selective methylation of compounds 3a-d using ethereal diazomethane, allowed the synthesis of isomers 4 and 5 which were useful intermediates for the preparation, by a simple approach, of the title compounds 7 and 9. A complete assignment of the chemical shifts to the carbon atoms of the compounds 7 and 9 was performed by different nmr experiments, such as DEPT and XHDEPT for onebond CH correlations and COLOC experiments for long-range C-H correlations.

chemistry.chemical_compoundchemistryDiazomethaneChemical shiftOrganic Chemistrychemistry.chemical_elementMethylationDEPTMedicinal chemistryCarbonJournal of Heterocyclic Chemistry
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ChemInform Abstract: Methylation of 2-Phenylamino-1,3,4-thiadiazole. A Structure Debated.

1987

The true identity of the 4-methyl-5-phenylimino-δ2-1,3,4-thiadiazoline (A) has been demonstrated. The reactions, previously reported in the literature to give A have been repeated and the structure of the compounds obtained has been established.

GeneticsChemistryIdentity (philosophy)media_common.quotation_subjectGeneral MedicineMethylationmedia_commonChemInform
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Methylation of 2-phenylamino-1,3,4-thiadiazole. A structure debated

1987

The true identity of the 4-methyl-5-phenylimino-δ2-1,3,4-thiadiazoline (A) has been demonstrated. The reactions, previously reported in the literature to give A have been repeated and the structure of the compounds obtained has been established.

Reaction mechanismChemistryStereochemistryIdentity (philosophy)media_common.quotation_subjectOrganic ChemistryMethylationmedia_commonJournal of Heterocyclic Chemistry
researchProduct

ChemInform Abstract: Synthesis and Spectroscopic Characterizations of Both 1-Ethyl-4,8- dihydro-10-methoxy-3-methyl-8-R1-6-R2-dipyrazolo(3,4-b:4′,3′-…

2010

The non-selective methylation of compounds 3a-d using ethereal diazomethane, allowed the synthesis of isomers 4 and 5 which were useful intermediates for the preparation, by a simple approach, of the title compounds 7 and 9. A complete assignment of the chemical shifts to the carbon atoms of the compounds 7 and 9 was performed by different nmr experiments, such as DEPT and XHDEPT for onebond CH correlations and COLOC experiments for long-range C-H correlations.

chemistry.chemical_compoundChemistryStereochemistryDiazomethaneChemical shiftchemistry.chemical_elementGeneral MedicineMethylationDEPTCarbonMedicinal chemistryChemInform
researchProduct