0000000000319901
AUTHOR
Jesús Ferrando−soria
Highly Efficient MOF-Driven Silver Subnanometer Clusters for the Catalytic Buchner Ring Expansion Reaction
The preparation of novel efficient catalysts-that could be applicable in industrially important chemical processes-has attracted great interest. Small subnanometer metal clusters can exhibit outstanding catalytic capabilities, and thus, research efforts have been devoted, recently, to synthesize novel catalysts bearing such active sites. Here, we report the gram-scale preparation of Ag2subnanometer clusters within the channels of a highly crystalline three-dimensional anionic metal-organic framework, with the formula [Ag2]@AgNa{Ni[Cu(Mempba)]}·48HO [Mempba= N,N′-2,4,6-trimethyl-1,3-phenylenebis(oxamate)]. The resulting crystalline solid catalyst-fully characterized with the help of single-c…
CCDC 2155456: Experimental Crystal Structure Determination
Related Article: Estefanía Tiburcio, Yongkun Zheng, Marta Mon, Nuria Martín, Jesús Ferrando−Soria, Donatella Armentano, Antonio Leyva−Pérez, Emilio Pardo|2022|Inorg.Chem.|61|11796|doi:10.1021/acs.inorgchem.2c01508
CCDC 2155455: Experimental Crystal Structure Determination
Related Article: Estefanía Tiburcio, Yongkun Zheng, Marta Mon, Nuria Martín, Jesús Ferrando−Soria, Donatella Armentano, Antonio Leyva−Pérez, Emilio Pardo|2022|Inorg.Chem.|61|11796|doi:10.1021/acs.inorgchem.2c01508
CCDC 1841425: Experimental Crystal Structure Determination
Related Article: Marta Mon, Rosa Adam, Jesús Ferrando−Soria, Avelino Corma, Donatella Armentano, Emilio Pardo, and Antonio Leyva−Pérez|2018|ACS Catalysis|8|10401|doi:10.1021/acscatal.8b03228