0000000000323008
AUTHOR
Sayantan Ganguly
Modulation of Nuclearity in Cu II −Mn II Complexes of a N 2 O 2 Donor Ligand Depending upon Carboxylate Anions: Structures, Magnetic Properties and Catalytic Oxidase Activities
Three new hetero-metallic copper(II)-manganese(II) complexes, [(CuL)2 Mn3 (C6 H5 CO2 )6 ] (1), [(CuL)2 Mn(CH3 CO2 )2 ] (2), and {[(CuL)2 Mn(C6 H5 CH2 CO2 )2 ] ⋅ 2CH3 CN} (3), have been synthesized using [CuL] as ''metalloligand'' (where H2 L=N,N'-bis(2-hydroxynaphthyl-methylidene)-1,3-propanediamine). Single-crystal structural analyses show an almost linear penta-nuclear structure for complex 1 where a square planar [CuL] unit is connected to each of the two terminal MnII ions of a linear, centrosymmetric [Mn3 (benzoate)6 ] unit through the double phenoxido bridges. Both complexes 2 and 3 possess a linear tri-nuclear structure where two terminal square-pyramidal [CuL] units are bonded to th…
CCDC 2008125: Experimental Crystal Structure Determination
Related Article: Sayantan Ganguly, Júlia Mayans, Ashutosh Ghosh|2020|Chem.Asian J.|15|4055|doi:10.1002/asia.202000706
CCDC 2008123: Experimental Crystal Structure Determination
Related Article: Sayantan Ganguly, Júlia Mayans, Ashutosh Ghosh|2020|Chem.Asian J.|15|4055|doi:10.1002/asia.202000706
CCDC 2008124: Experimental Crystal Structure Determination
Related Article: Sayantan Ganguly, Júlia Mayans, Ashutosh Ghosh|2020|Chem.Asian J.|15|4055|doi:10.1002/asia.202000706