0000000000323232
AUTHOR
Volker Gebhardt
Relationship between structure and electroluminescence of oligo(p-phenylenevinylene)s
The preparation of LEDs with poly(p-phenylenevinylene) (PPV) as emitting material is well established, However, due to the presence of a distribution of conjugated chain lengths in the polymer, systematic investigations of the electroluminescence with polymeric materials are difficult, as far as the optical emission is concerned. We are studying the relationship between structural variation of substituted oligo(p-phenylenevinylene)s and their electroluminescent behaviour using a series of distyrylbenzenes with a variety of substituents in order to investigate their influence on the electroluminescence (EL). Furthermore, we synthesized a homologous series of monodisperse oligo(2,5-dipropoxy-…
Finite index subgroups of mapping class groups
Let g ≥ 3 and n ≥ 0, and let Mg,n be the mapping class group of a surface of genus g with n boundary components. We prove that Mg,n contains a unique subgroup of index 2g−1(2g − 1) up to conjugation, a unique subgroup of index 2g−1(2g + 1) up to conjugation, and the other proper subgroups ofMg,n are of index greater than 2g−1(2g+1). In particular, the minimum index for a proper subgroup of Mg,n is 2g−1(2g − 1). AMS Subject Classification. Primary: 57M99. Secondary: 20G40, 20E28. 0 Introduction and statement of results The interaction between mapping class groups and finite groups has long been a topic of interest. The famous Hurwitz bound of 1893 showed that the mapping class group of a clo…
Light-emitting diodes based on phenylenevinylene oligomers with defined chain lengths
Abstract We present characteristic electroluminescence data on single-layer devices based on three different oligo phenylenevinylene compounds with defined chain lengths. Light-emitting diodes (LEDs) were prepared by subsequent vacuum evaporation of the oligomer film and the A1 top electrode onto an indium—tin oxide (ITO) substrate. The LEDs show light emission in the spectral range of yellow to orange depending on the conjugation length of the compound used. We report photoluminescence and optical absorption data of the thin sublimed films, together with the wavelength dependence of the electroluminescence and with the current—voltage characteristics of the LED devices. The redox behavior …