0000000000323840

AUTHOR

Konstantin V. Domasevitch

showing 2 related works from this author

Fast detection of water and organic molecules by a change of color in an iron(II) microporous spin-crossover coordination polymer.

2012

Here we present a novel three-dimensional iron(II) spin-crossover porous coordination polymer based on the bis(1,2,4-triazol-4-yl)adamantane (tr(2)ad) ligand and the [Au(CN)(2)](-) metalloligand anions with the formula {Fe(3)(tr(2)ad)(4)[Au(CN)(2))](2)}[Au(CN)(2)](4)·G. The sorption/desorption of guest molecules, water, and five/six-membered-ring organic molecules is easily detectable because the guest-free and -loaded frameworks present drastically distinct coloration and spin-state configurations.

Coordination polymerLigandAdamantaneInorganic chemistrySorptionMicroporous materialInorganic Chemistrychemistry.chemical_compoundCrystallographychemistrySpin crossoverDesorptionMoleculePhysical and Theoretical ChemistryInorganic chemistry
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Crystal structure of cis-bis­(μ-β-alanine-κ2 O:O′)bis[tri­chlorido­rhenium(III)](Re–Re) sesquihydrate

2015

A dirhenium(III) cis-di­carboxyl­ate complex is reported, which is representative of a small class of zwitterionic ammonia­carboxyl­ato complexes involving a quadruple metal–metal bond.

crystal structurechemistry.chemical_elementCrystal structurerheniumChlorideIonResearch CommunicationsCrystallcsh:Chemistryquadruple metal–metal bondmedicineMoleculeGeneral Materials ScienceclusterAlanineLigandGeneral ChemistryRheniumCondensed Matter PhysicsCrystallographychemistrylcsh:QD1-999β-alaninezwitterionic ammonia­carboxyl­ato complexzwitterionic ammoniacarboxylato complexmedicine.drugActa Crystallographica Section E: Crystallographic Communications
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