Femtosecond four-wave-mixing spectroscopy of suspended individual semiconducting single-walled carbon nanotubes.
Femtosecond four-wave-mixing (FWM) experiments of individual suspended semiconducting single-walled carbon nanotubes (SWCNTs) are presented. The chiral indices of the tubes were determined by electron diffraction as (28,14) and (24,14) having diameters of 2.90 and 2.61 nm, respectively. The diameter and semiconducting character of the tubes were additionally confirmed by resonance Raman measurements. The FWM signal showed electronic response from the SWCNTs. The results demonstrate that ultrafast dynamics of individual SWCNTs can be studied by FWM spectroscopies.
Second-harmonic Generation Microscopy of Carbon Nanotubes
We image an individual single-walled carbon nanotube (SWNT) by second-harmonic generation (SHG) and transmission electron microscopy and propose that SHG microscopy could be used to probe the handedness of chiral SWNTs.
Measurement of optical second-harmonic generation from an individual single-walled carbon nanotube
We show that optical second-harmonic generation (SHG) can be observed from individual single-walled carbon nanotubes (SWCNTs) and, furthermore, allows imaging of individual tubes. Detailed analysis of our results suggests that the structural noncentrosymmetry, as required for SHG, arises from the non-zero chiral angle of the SWCNT. SHG thus has potential as a fast, non-destructive, and simple method for imaging of individual nanomolecules and for probing their chiral properties. Even more, it opens the possibility to optically determine the handedness of individual SWCNTs.