0000000000335424
AUTHOR
Edgars Smalins
Estimation of the emission temperature of an electrodeless discharge lamp and determination of the oscillator strength for the I(2P3/2) 183.038 nm resonance transition
Abstract The 183.038 nm resonance absorption transition of I( 2 P 3/2 ) has been studied using a flash photolysis set-up for gas-phase chemistry and a radio frequency powered electrodeless discharge lamp filled with iodine. The dependence of self-absorption and self-reversal on iodine partial pressure in the discharge volume was measured. The optimum iodine partial pressure, with self-absorption minimized and acceptable intensity, is determined to be approximately 2.5×10 −3 mbar. A method is described to estimate the temperature of the emitting atoms using direct measurements of relative absorption at different absorber concentrations. This yields an emission temperature of 923±50 K. Using …
<title>Iodine and bromine resonance lamps in atmospheric research</title>
For the first time previously developed iodine resonance spectra source has been tested in flash photolysis experiment. Quantitative measurements of concentration kinetics of iodine atomic species in a I2+O3 system are possible. The 183.038 nm resonance absorption transition of I(2P3/2) in previously developed EDL has been studied; dependence of self-absorption and self-reversal on iodine partial pressure in the discharge volume has been measured. The search for optimal conditions for an iodine EDL with minimized self-absorption and sufficient intensity were made. In condition of flash photolysis with previously described method it is possible to determine the emission temperature, oscillat…
A Ground Validation Station for the Satellite-based Atmospheric Sensor Instruments GOME and SCIAMACHY
The development of a DOAS based ground validation station for satellite based atmospheric sensor instruments GOME and SCIMACHY at the Institute of Atomic Physics and Spectroscopy, University of Latvia, is now underway. The activity has to look to the future by: — the development of co-operation with the European research community in atmospheric science contributing to the valuable infrastructure for common needs; and — a building up of the capacity of the team (through research training of students) to become a strong partner in the future.