0000000000339228
AUTHOR
M. R. Abargues
Removal and fate of endocrine disruptors chemicals under lab-scalepostreatment stage. Removal assessment using light, oxygen and microalgae
[EN] The aim of this study was to assess the effect of light, oxygen and microalgae on micropollutants removal. The studied micropollutants were 4-(1,1,3,3-tetramethylbutyl)phenol (OP), technical-nonylphenol (t-NP), 4-n-nonylphenol (4-NP), Bisphenol-A (BPA). In order to study the effect of the three variables on the micropollutants removal, a factorial design was developed. The experiments were carried out in four batch reactors which treated the effluent of an anaerobic membrane bioreactor. The gas chromatography mass spectrometry was used for the measurement of the micropollutants. The results showed that light, oxygen and microalgae affected differently to the degradation ratios of each …
Guidelines for alkylphenols estimation as alkylphenol polyethoxylates pollution indicator in wastewater treatment plant effluents
A solid-phase microextraction coupled with a gas chromatography-mass spectrometry method has been developed for the estimation of technical nonylphenol in the presence of other endocrine disruptors, belonging to different chemical families. The profile of the technical nonylphenol found in real samples was tested, and, given that it was similar to that provided for the standard used, reliable results were obtainable. Endocrine disruptors such as 4-n-nonylphenol, bisphenol A and 4-tert-octylphenol were simultaneously analysed. The best conditions achieved enabled the analysis of all analytes using a sample volume of 15 mL or even only 300 μL. Using such a low sample volume reduced the filtra…
Endocrine disrupter compounds removal in wastewater using microalgae: Degradation kinetics assessment
[EN] This paper describes a study carried out to determine the removal kinetics of four micropollutants (4-tert-octylphenol (OP), technical-nonylphenol (t-NP), 4-nonylphenol (4-NP) and bisphenol-A (BPA)) usually found in wastewater streams. The kinetic experiments were carried out in batch reactors containing the effluent of an Anaerobic Membrane BioReactor (AnMBR) in the presence of light, oxygen and microalgae. As the degradation process of the studied micropollutants obeyed a pseudo-first-order kinetics, the second-order kinetics for each micropollutant was then calculated. The second order rate constants for the hydroxyl radical (k.(OH)) ranged from 7.0.10(+10) to 6.6.10(+12) L.mol(-1).…
Fate of endocrine disruptor compounds in an anaerobic membrane bioreactor (AnMBR) coupled to an activated sludge reactor
[EN] The occurrence and fate of three groups of micropollutants - alkylphenols, pentachlorophenol and hormones - were studied in a pilot plant consisting of an anaerobic membrane bioreactor (AnMBR) coupled to an activated sludge reactor (University of Cape Town configuration - UCT). Under anaerobic conditions, the octylphenol and technical-nonylphenol soluble concentrations increased producing negative degradation ratios (i.e., -175 and -118%, respectively). However, high 4-n-nonylphenol and bisphenol-A degradation ratios (92 and 59% for 4-n-nonylphenol and bisphenol-A, respectively) as well as complete pentachlorophenol, estrone, 17 beta-estradiol and 17 alpha-ethinylestradiol removal were…
Micropollutants removal in an anaerobic membrane bioreactor and in an aerobic conventional treatment plant
The paper expresses an attempt to tackle the problem due to the presence of micropollutants in wastewater which may be able to disrupt the endocrine system of some organisms. These kinds of compounds are ubiquitously present in municipal wastewater treatment plant (WWTP) effluents. The aim of this paper is to compare the fate of the alkylphenols-APs (4-(tert-octyl)) phenol, t-nonylphenol and 4-p-nonylphenol and the hormones (estrone, 17ß-estradiol and 17¿-ethinylestradiol) in a submerged anaerobic membrane bioreactor (SAMBR) pilot plant and in a conventional activated sludge wastewater treatment plant (CTP). The obtained results are also compared with the results obtained in a previous stud…