0000000000340532
AUTHOR
Leonid S. Vlasenko
Series of Near-IR-Absorbing Transition Metal Complexes with Redox Active Ligands
New soluble and intensely near-IR-absorbing transition metal (Ti, Zr, V, Ni) complexes were synthesized using a redox non-innocent N,N&rsquo
NIR-absorbing transition metal complexes with redox-active ligands
Bench top stable transition metal (M = Co, Ni, Cu) complexes with a non-innocent ortho-aminophenol derivative were synthesized by the reaction of metal(II)acetates with a ligand precursor in 2:1 ratio. The solid-state structures reveal the formation of neutral molecular complexes with square planar coordination geometries. The Co(II) and Cu(II) complexes are paramagnetic, whereas the Ni complex is a diamagnetic square planar low-spin Ni(II) complex. All complexes, and Ni(II) complex in particular, show strong absorption in the near-IR region. Peer reviewed
CCDC 1986213: Experimental Crystal Structure Determination
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CCDC 1986216: Experimental Crystal Structure Determination
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CCDC 1986214: Experimental Crystal Structure Determination
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CCDC 1986215: Experimental Crystal Structure Determination
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CCDC 1913766: Experimental Crystal Structure Determination
Related Article: Esko Salojärvi, Anssi Peuronen, Hannu Huhtinen, Leonid S. Vlasenko, Janne Halme, Pyry Mäkinen, Mika Lastusaari, Ari Lehtonen|2020|Inorg.Chem.Commun.|112|107711|doi:10.1016/j.inoche.2019.107711
CCDC 1913765: Experimental Crystal Structure Determination
Related Article: Esko Salojärvi, Anssi Peuronen, Hannu Huhtinen, Leonid S. Vlasenko, Janne Halme, Pyry Mäkinen, Mika Lastusaari, Ari Lehtonen|2020|Inorg.Chem.Commun.|112|107711|doi:10.1016/j.inoche.2019.107711
CCDC 1987795: Experimental Crystal Structure Determination
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