0000000000343858
AUTHOR
Marcos A. Ribeiro
A two-dimensional oxamate- and oxalate-bridged Cu(II)Mn(II) motif: crystal structure and magnetic properties of (Bu4N)2[Mn2{Cu(opba)}2ox].
A new compound of formula (Bu4N)2[Mn2{Cu(opba)}2ox] (1) [Bu4N(+) = tetra-n-butylammonium cation, H4opba = 1,2-phenylenebis(oxamic acid), and H2ox = oxalic acid] has been synthesized and magneto-structurally investigated. The reaction of manganese(II) acetate, [Cu(opba)](2-), and ox(2-) in dimethyl sulfoxide yielded single crystals of 1. The structure of 1 consists of heterobimetallic oxamato-bridged Cu(II)Mn(II) chains which are connected through bis-bidentate oxalate coordinated to the manganese(II) ions to afford anionic heterobimetallic layers of 6(3)-hcb net topology. The layers are interleaved by n-Bu4N(+) counterions. Each copper(II) ion in 1 is four-coordinate in a square planar envi…
Palladium(II)–Copper(II) Assembling with Bis(2-pyridylcarbonyl)amidate and Bis(oxamate) Type Ligands
Five new complexes of formula K4[Pd2(mpba)2] · 4H2O (1), {[K4(H2O)(dmso)][Pd2(mpba)2]} (2), {[Cu(bpca)]4[Pd2(mpba)2]} · 6H2O (3), {[Cu(bpca)]2[Pd(opba)]} · 1.75dmso · 0.25H2O (4), {[Cu(bpca)]2[Pd(opba)]}n · ndmso (5) [H4mpba =1,3-phenylenebis(oxamic acid), H4opba = 1,2-phenylenebis(oxamic acid), Hbpca = bis(2-pyridylcarbonyl)amide, and dmso = dimethyl sulfoxide] have been prepared and investigated by infrared spectroscopy, thermal analysis, single crystal X-ray diffraction, and magnetic susceptibility techniques. The structure of 2 consists of a [Pd2(mpba)2]4– anionic entity in which the palladium(II) cations are coordinated by two mpba ligands resulting in a dipalladium(II) unit that acts …
Polymorphic Derivatives of NiII and CoII Mesocates with 3D Networks and “Brick and Mortar” Structures: Preparation, Structural Characterization, and Cryomagnetic Investigation of New Single-Molecule Magnets
In this work we describe the preparation, spectroscopic, thermal and structural characterization, and cryomagnetic investigation of four new polymorphic derivatives of the [M2(H2mpba)3]2– mesocate ...
Copper(II) assembling with bis(2-pyridylcarbonyl)amidate and N,N'-2,2-phenylenebis(oxamate).
We herein present the synthesis and X-ray structures of five copper(II) complexes of formulae [Cu(bpca)(CF3SO3)(H2O)]·H2O (1), [Cu(bpca)(Phpr)(H2O)]·3/2H2O (2), {[Cu(bpca)]2[Cu(opba)(H2O)]}·H2O (3), {[Cu(bpca)]2(H2opba)}2·6H2O (4) and [Cu(bpca)(EtH2opba)]n (5), where bpca = bis(2-pyridylcarbonyl)amidate, Phpr = 3-phenylpropionate, CF3SO3(−) = triflate (anion of the trifluoromethanesulphonic acid), H4opba = N,N′-1,2-phenylenebis(oxamic acid), and EtH3opba = monoethyl ester derivative of the H4opba. 1 and 2 are mononuclear copper(II) complexes where the copper atom is five-coordinate in distorted square pyramidal surroundings with a tridentate bpca and a water molecule (1)/carboxylate oxygen …
Study of the complex formation between the [Cu(bpca)]+ secondary building unit and the aromatic N donors 2,3,5,6-tetra(2-pyridyl)pyrazine (tppz) and 1,3-bis(4-pyridyl)propane (bpp)
Two new complexes of the formula [{Cu(bpca)}2(μ-tppz)](NO3)2·5H2O (1) and [Cu(bpca)(H2O)(ClO4)(μ-bpp)Cu(bpca)(H2O)2]ClO4·H2O (2) [tppz = 2,3,5,6-tetra(2-pyridyl)pyrazine and bpp = 1,3-bis(4-pyridyl)propane] have been prepared by the reaction of the [Cu(bpca)]+ [Hbpca = bis(2-pyridylcarbonyl)imide] building block and the tppz and bpp N donors. An unusual coordination mode of the tppz ligand was observed in 1, which functions as a bis(bidentate) ligand to two copper(II) atoms each coordinated to a nitrogen atom of the pyrazine moiety and a pyridyl nitrogen atom. This compound presents a layered structure of alternating anionic (ca. 1.6 A) and cationic (ca. 10 A) slices, providing the opportun…
A pH-triggered bistable copper(II) metallacycle as a reversible emulsion switch for biphasic processes.
A unique bistable copper-metallacyclic complex is used as an elegant molecular switch for the reversible formation of emulsions by simple pH variation. This switch may have several exciting applications in biphasic processes such as catalysis and separation science technologies.
Magneto‐Structural Study of an Oxamato‐Bridged Pd II Co II Chain: X‐ray Crystallographic Evidence of a Single‐Crystal‐to‐Single‐Crystal Phase Transition
Two new mononuclear oxamato-containing palladium(II) complexes of formula K2[Pd(opba)]·2H2O (1) and (PPh4)2[Pd(opba)]·2H2O (2) and the heterodimetallic palladium(II)–cobalt(II) chain {[Co(H2O)2Pd(opba)]·dmso}n (3) [opba = 1,2-phenylenebis(oxamate), PPh4+ = tetraphenylphosphonium cation and dmso = dimethyl sulfoxide] have been prepared, and the structures of two of them (compounds 2 and 3) were determined by X-ray diffraction analysis of single crystals. The structure of 2 consists of discrete anions of [Pd(opba)2]2– and PPh4+ cations. Each PdII ion in 2 is surrounded by two oxamate nitrogen atoms and two carboxylate oxygen atoms in a square-planar surrounding. Compound 3 is a neutral chain …
Magneto-structural versatility of copper(II)-3-phenylpropionate coordination polymers with N-donor coligands.
A novel series of copper(II) coordination polymers [Cu2(O2CC8H9)4(pyz)]n (1), [Cu2(O2CC8H9)4(dps)]n (2), {[Cu(O2CC8H9)2(dps)(H2O)]·H2O}n (3), {[NaCu(O2CC8H9)2(bpm)(NO3)]·H2O}n (4), and [Cu4(O2CC8H9)6(OH)2(bpp)2]n (5) [O2CC8H9− = 3-phenylpropionate anion, pyz = pyrazine, dps = di(4-pyridyl)sulfide, bpm = 2,2′-bipyrimidine, and bpp = 1,3-bis(4-pyridyl)propane] have been synthesized and magneto-structurally investigated. Compounds 1 and 2 belong to a large group of copper(II) carboxylates where bis-monodentate pyz (1) and dps (2) ligands connect the paddle-wheel [CuII2(μ-O2CC8H9)4] units leading to alternating copper(II) chains. The structure of 3 consists of uniform chains of trans-[CuII(O2CC…
CCDC 1034456: Experimental Crystal Structure Determination
Related Article: Willian X. C. Oliveira, Marcos A. Ribeiro, Carlos B. Pinheiro, Marinez M. da Costa, Ana Paula S. Fontes, Wallace C. Nunes, Danielle Cangussu, Miguel Julve, Humberto O. Stumpf, Cynthia L. M. Pereira|2015|Cryst.Growth Des.|15|1325|doi:10.1021/cg5017388
CCDC 1898457: Experimental Crystal Structure Determination
Related Article: Ludmila dos S. Mariano, Iara M. L. Rosa, Nathália R. De Campos, Antônio C. Doriguetto, Danielle F. Dias, Walace D. do Pim, Ana Karoline S.M. Valdo, Felipe T. Martins, Marcos A. Ribeiro, Elgte E. B. De Paula, Emerson F. Pedroso, Humberto O. Stumpf, Joan Cano, Francesc Lloret, Miguel Julve, Maria Vanda Marinho|2020|Cryst.Growth Des.|20|2462|doi:10.1021/acs.cgd.9b01638
CCDC 909392: Experimental Crystal Structure Determination
Related Article: Tatiana R.G. Simoes, Raquel V. Mambrini, Daniella O. Reis,Maria V. Marinho, Marcos A. Ribeiro, Carlos B. Pinheiro, Jesus Ferrando-Soria, Mariadel Deniz, Catalina Ruiz-Perez, Danielle Cangussu,Humberto O. Stumpf, Francesc Lloret, Miguel Julve|2013|Dalton Trans.|42|5778|doi:10.1039/C3DT32949F
CCDC 1898455: Experimental Crystal Structure Determination
Related Article: Ludmila dos S. Mariano, Iara M. L. Rosa, Nathália R. De Campos, Antônio C. Doriguetto, Danielle F. Dias, Walace D. do Pim, Ana Karoline S.M. Valdo, Felipe T. Martins, Marcos A. Ribeiro, Elgte E. B. De Paula, Emerson F. Pedroso, Humberto O. Stumpf, Joan Cano, Francesc Lloret, Miguel Julve, Maria Vanda Marinho|2020|Cryst.Growth Des.|20|2462|doi:10.1021/acs.cgd.9b01638
CCDC 909388: Experimental Crystal Structure Determination
Related Article: Tatiana R.G. Simoes, Raquel V. Mambrini, Daniella O. Reis,Maria V. Marinho, Marcos A. Ribeiro, Carlos B. Pinheiro, Jesus Ferrando-Soria, Mariadel Deniz, Catalina Ruiz-Perez, Danielle Cangussu,Humberto O. Stumpf, Francesc Lloret, Miguel Julve|2013|Dalton Trans.|42|5778|doi:10.1039/C3DT32949F
CCDC 923163: Experimental Crystal Structure Determination
Related Article: Maria V. Marinho, Tatiana R. G. Simões, Marcos A. Ribeiro, Cynthia L. M. Pereira, Flávia C. Machado, Carlos B. Pinheiro, Humberto O. Stumpf, Joan Cano, Francesc Lloret, and Miguel Julve|2013|Inorg.Chem.|52|8812|doi:10.1021/ic401038c
CCDC 1559171: Experimental Crystal Structure Determination
Related Article: Eloisa O. Ribeiro, Nathália R. de Campos, Antônio C. Doriguetto, Wdeson P. Barros, Marcos A. Ribeiro, Elgte E. B. De Paula, Humberto O. Stumpf, Francesc Lloret, Miguel Julve, Maria V. Marinho|2017|CrystEngComm|19|5460|doi:10.1039/C7CE01230F
CCDC 927505: Experimental Crystal Structure Determination
Related Article: Walace D. do Pim, Willian X. C. Oliveira, Marcos A. Ribeiro, Érica N. de Faria, Ivo F. Teixeira, Humberto O. Stumpf, Rochel M. Lago, Cynthia L. M. Pereira, Carlos B. Pinheiro, João C. D. Figueiredo-Júnior, Wallace C. Nunes, Patterson P. de Souza, Emerson F. Pedroso, María Castellano, Joan Cano, Miguel Julve|2013|Chem.Commun.|49|10778|doi:10.1039/C3CC46242K
CCDC 1898454: Experimental Crystal Structure Determination
Related Article: Ludmila dos S. Mariano, Iara M. L. Rosa, Nathália R. De Campos, Antônio C. Doriguetto, Danielle F. Dias, Walace D. do Pim, Ana Karoline S.M. Valdo, Felipe T. Martins, Marcos A. Ribeiro, Elgte E. B. De Paula, Emerson F. Pedroso, Humberto O. Stumpf, Joan Cano, Francesc Lloret, Miguel Julve, Maria Vanda Marinho|2020|Cryst.Growth Des.|20|2462|doi:10.1021/acs.cgd.9b01638
CCDC 1034455: Experimental Crystal Structure Determination
Related Article: Willian X. C. Oliveira, Marcos A. Ribeiro, Carlos B. Pinheiro, Marinez M. da Costa, Ana Paula S. Fontes, Wallace C. Nunes, Danielle Cangussu, Miguel Julve, Humberto O. Stumpf, Cynthia L. M. Pereira|2015|Cryst.Growth Des.|15|1325|doi:10.1021/cg5017388
CCDC 1409933: Experimental Crystal Structure Determination
Related Article: Nathália R. de Campos, Marcos A. Ribeiro, Willian X. C. Oliveira, Daniella O. Reis, Humberto O. Stumpf, Antônio C. Doriguetto, Flávia C. Machado, Carlos B. Pinheiro, Francesc Lloret, Miguel Julve, Joan Cano, Maria V. Marinho|2016|Dalton Trans.|45|172|doi:10.1039/C5DT03401A
CCDC 927507: Experimental Crystal Structure Determination
Related Article: Walace D. do Pim, Willian X. C. Oliveira, Marcos A. Ribeiro, Érica N. de Faria, Ivo F. Teixeira, Humberto O. Stumpf, Rochel M. Lago, Cynthia L. M. Pereira, Carlos B. Pinheiro, João C. D. Figueiredo-Júnior, Wallace C. Nunes, Patterson P. de Souza, Emerson F. Pedroso, María Castellano, Joan Cano, Miguel Julve|2013|Chem.Commun.|49|10778|doi:10.1039/C3CC46242K
CCDC 1409935: Experimental Crystal Structure Determination
Related Article: Nathália R. de Campos, Marcos A. Ribeiro, Willian X. C. Oliveira, Daniella O. Reis, Humberto O. Stumpf, Antônio C. Doriguetto, Flávia C. Machado, Carlos B. Pinheiro, Francesc Lloret, Miguel Julve, Joan Cano, Maria V. Marinho|2016|Dalton Trans.|45|172|doi:10.1039/C5DT03401A
CCDC 1034458: Experimental Crystal Structure Determination
Related Article: Willian X. C. Oliveira, Marcos A. Ribeiro, Carlos B. Pinheiro, Marinez M. da Costa, Ana Paula S. Fontes, Wallace C. Nunes, Danielle Cangussu, Miguel Julve, Humberto O. Stumpf, Cynthia L. M. Pereira|2015|Cryst.Growth Des.|15|1325|doi:10.1021/cg5017388
CCDC 909389: Experimental Crystal Structure Determination
Related Article: Tatiana R.G. Simoes, Raquel V. Mambrini, Daniella O. Reis,Maria V. Marinho, Marcos A. Ribeiro, Carlos B. Pinheiro, Jesus Ferrando-Soria, Mariadel Deniz, Catalina Ruiz-Perez, Danielle Cangussu,Humberto O. Stumpf, Francesc Lloret, Miguel Julve|2013|Dalton Trans.|42|5778|doi:10.1039/C3DT32949F
CCDC 927506: Experimental Crystal Structure Determination
Related Article: Walace D. do Pim, Willian X. C. Oliveira, Marcos A. Ribeiro, Érica N. de Faria, Ivo F. Teixeira, Humberto O. Stumpf, Rochel M. Lago, Cynthia L. M. Pereira, Carlos B. Pinheiro, João C. D. Figueiredo-Júnior, Wallace C. Nunes, Patterson P. de Souza, Emerson F. Pedroso, María Castellano, Joan Cano, Miguel Julve|2013|Chem.Commun.|49|10778|doi:10.1039/C3CC46242K
CCDC 909390: Experimental Crystal Structure Determination
Related Article: Tatiana R.G. Simoes, Raquel V. Mambrini, Daniella O. Reis,Maria V. Marinho, Marcos A. Ribeiro, Carlos B. Pinheiro, Jesus Ferrando-Soria, Mariadel Deniz, Catalina Ruiz-Perez, Danielle Cangussu,Humberto O. Stumpf, Francesc Lloret, Miguel Julve|2013|Dalton Trans.|42|5778|doi:10.1039/C3DT32949F
CCDC 1409934: Experimental Crystal Structure Determination
Related Article: Nathália R. de Campos, Marcos A. Ribeiro, Willian X. C. Oliveira, Daniella O. Reis, Humberto O. Stumpf, Antônio C. Doriguetto, Flávia C. Machado, Carlos B. Pinheiro, Francesc Lloret, Miguel Julve, Joan Cano, Maria V. Marinho|2016|Dalton Trans.|45|172|doi:10.1039/C5DT03401A
CCDC 1559172: Experimental Crystal Structure Determination
Related Article: Eloisa O. Ribeiro, Nathália R. de Campos, Antônio C. Doriguetto, Wdeson P. Barros, Marcos A. Ribeiro, Elgte E. B. De Paula, Humberto O. Stumpf, Francesc Lloret, Miguel Julve, Maria V. Marinho|2017|CrystEngComm|19|5460|doi:10.1039/C7CE01230F
CCDC 1409932: Experimental Crystal Structure Determination
Related Article: Nathália R. de Campos, Marcos A. Ribeiro, Willian X. C. Oliveira, Daniella O. Reis, Humberto O. Stumpf, Antônio C. Doriguetto, Flávia C. Machado, Carlos B. Pinheiro, Francesc Lloret, Miguel Julve, Joan Cano, Maria V. Marinho|2016|Dalton Trans.|45|172|doi:10.1039/C5DT03401A
CCDC 1898456: Experimental Crystal Structure Determination
Related Article: Ludmila dos S. Mariano, Iara M. L. Rosa, Nathália R. De Campos, Antônio C. Doriguetto, Danielle F. Dias, Walace D. do Pim, Ana Karoline S.M. Valdo, Felipe T. Martins, Marcos A. Ribeiro, Elgte E. B. De Paula, Emerson F. Pedroso, Humberto O. Stumpf, Joan Cano, Francesc Lloret, Miguel Julve, Maria Vanda Marinho|2020|Cryst.Growth Des.|20|2462|doi:10.1021/acs.cgd.9b01638
CCDC 909391: Experimental Crystal Structure Determination
Related Article: Tatiana R.G. Simoes, Raquel V. Mambrini, Daniella O. Reis,Maria V. Marinho, Marcos A. Ribeiro, Carlos B. Pinheiro, Jesus Ferrando-Soria, Mariadel Deniz, Catalina Ruiz-Perez, Danielle Cangussu,Humberto O. Stumpf, Francesc Lloret, Miguel Julve|2013|Dalton Trans.|42|5778|doi:10.1039/C3DT32949F
CCDC 1034457: Experimental Crystal Structure Determination
Related Article: Willian X. C. Oliveira, Marcos A. Ribeiro, Carlos B. Pinheiro, Marinez M. da Costa, Ana Paula S. Fontes, Wallace C. Nunes, Danielle Cangussu, Miguel Julve, Humberto O. Stumpf, Cynthia L. M. Pereira|2015|Cryst.Growth Des.|15|1325|doi:10.1021/cg5017388
CCDC 1409936: Experimental Crystal Structure Determination
Related Article: Nathália R. de Campos, Marcos A. Ribeiro, Willian X. C. Oliveira, Daniella O. Reis, Humberto O. Stumpf, Antônio C. Doriguetto, Flávia C. Machado, Carlos B. Pinheiro, Francesc Lloret, Miguel Julve, Joan Cano, Maria V. Marinho|2016|Dalton Trans.|45|172|doi:10.1039/C5DT03401A