0000000000343984
AUTHOR
Ewa Pacholska
Improved routes for the synthesis of face-to-face bismacrocycles in porphyrin and corrole series
Face-to-face bismacrocycles involving porphyrinoid species are still of great interest owing to their versatile properties. Despite the fact that their syntheses generally involve several steps, numerous modifications have been made in their synthetic pathways thus allowing their preparation in gram quantities. Here we report on recent improvements we could propose especially for the synthesis of bisporphyrin, biscorrole and porphyrin-corrole derivatives.
New route to a face-to-face biscorrole free-base and the corresponding heterobimetallic copper(III)-silver(III) complex.
A meso-aryl-substituted face-to-face biscorrole was synthesised in a two-step reaction and the corresponding homo- and heterobimetallic complexes were obtained and fully characterised.