0000000000345439
AUTHOR
Jarno Linnera
showing 16 related works from this author
Cleavage of Ge–Ge and Sn–Sn Triple Bonds in Heavy Group 14 Element Alkyne Analogues (EAriPr4)2 (E = Ge, Sn; AriPr4 = C6H3-2,6(C6H3-2,6-iPr2)2) by Rea…
2016
The reactions of heavier group 14 element alkyne analogues (EAriPr4)2 (E = Ge, Sn; AriPr4 = C6H3-2,6-(C6H3-2,6-iPr2)2) with the group 6 transition-metal carbonyls M(CO)6 (M = Cr, Mo, W) under UV irradiation resulted in the cleavage of the E–E triple bond and the formation of the complexes {AriPr4EM(CO)4}2 (1–6), which were characterized by single crystal X-ray diffraction as well as by IR and multinuclear NMR spectroscopy. Single-crystal X-ray structural analyses of 1–6 showed that the complexes have a nearly planar rhomboid M2E2 core with three-coordinate group 14 atoms. The coordination geometry at the group 6 metals is distorted octahedral formed by four carbonyl groups as well as two br…
Cleavage of Ge–Ge and Sn–Sn Triple Bonds in Heavy Group 14 Element Alkyne Analogues (EAriPr4)2 (E = Ge, Sn; AriPr4 = C6H3-2,6(C6H3-2,6-iPr2)2) by Rea…
2016
The reactions of heavier group 14 element alkyne analogues (EAriPr4)2 (E = Ge, Sn; AriPr4 = C6H3-2,6-(C6H3-2,6-iPr2)2) with the group 6 transition-metal carbonyls M(CO)6 (M = Cr, Mo, W) under UV irradiation resulted in the cleavage of the E–E triple bond and the formation of the complexes {AriPr4EM(CO)4}2 (1–6), which were characterized by single crystal X-ray diffraction as well as by IR and multinuclear NMR spectroscopy. Single-crystal X-ray structural analyses of 1–6 showed that the complexes have a nearly planar rhomboid M2E2 core with three-coordinate group 14 atoms. The coordination geometry at the group 6 metals is distorted octahedral formed by four carbonyl groups as well as two br…
Synthesis, structure and photophysical properties of a highly luminescent terpyridine-diphenylacetylene hybrid fluorophore and its metal complexes
2014
A new fluorescent terpyridyl-diphenylacetylene hybrid fluorophore 4'-[4-{(4-methoxyphenyl)ethynyl}phenyl]-2,2':6',2''-terpyridine, L, was synthesized via Sonogashira cross-coupling of 4'-(4-bromophenyl)-2,2':6',2''-terpyridine and 4-ethynylanisole in the presence of Pd(PPh3)4/CuI as a catalyst. The solid state structure of L shows a trans arrangement of pyridine nitrogen atoms along the interannular bond in the terpyridine domain. Five transition metal complexes of L, {[FeL2](CF3SO3)2 (1), [ZnL2](ClO4)2 (2), [CdL2](ClO4)2 (3), [RuL2](PF6)2 (4), and PtMe3IL (5)}, have also been synthesized and characterized by spectroscopic methods and single crystal X-ray analysis. The X-ray crystal structu…
Synthesis, structure and photophysical properties of a highly luminescent terpyridine-diphenylacetylene hybrid fluorophore and its metal complexes
2015
A new fluorescent terpyridyl-diphenylacetylene hybrid fluorophore 4′-[4-{(4-methoxyphenyl)ethynyl}phenyl]-2,2′:6′,2′′-terpyridine, L, was synthesized via Sonogashira cross-coupling of 4′-(4-bromophenyl)-2,2′:6′,2′′-terpyridine and 4-ethynylanisole in the presence of Pd(PPh3)4/CuI as a catalyst. The solid state structure of L shows a trans arrangement of pyridine nitrogen atoms along the interannular bond in the terpyridine domain. Five transition metal complexes of L, {[FeL2](CF3SO3)2 (1), [ZnL2](ClO4)2 (2), [CdL2](ClO4)2 (3), [RuL2](PF6)2 (4), and PtMe3IL (5)}, have also been synthesized and characterized by spectroscopic methods and single crystal X-ray analysis. The X-ray crystal structu…
Atomikerroskasvatuksen ymmärrys molekyylitasolla
2014
Tutkielmassa käydään lyhyesti läpi atomikerroskasvatuksen historia, mitä se on ja sivutaan myös sen käyttökohteita. Atomikerroskasvatus on teollisessa mittakaavassa merkittävä sovellus ja sen käyttökohteiden määrä kasvaa entisestään. Pääosin keskitytään kahden yleisimmin käytetyn yhdisteen, alumiinioksidin Al2O3 ja hafniumoksidin HfO2, kasvatukseen, niiden reaktiomekanismeihin ja siihen kuinka reaktiomekanismit on saatu selville. Kronologinen läpileikkaus alkaen ensimmäisistä tehdyistä reaktioista aina viimeisimpiin ominaisuuksien selvittämistä koskeviin ja atomitason reaktioita kuvaaviin tutkimustuloksiin antaa yleiskuvan siitä kuinka monipuolisesta teknologiasta on kysymys. Tutkielmassa k…
CCDC 1505083: Experimental Crystal Structure Determination
2016
Related Article: Madison L. McCrea-Hendrick, ChristineA. Caputo, Jarno Linnera, Petra Vasko, CoryM. Weinstein, James C. Fettinger, Heikki M. Tuononen, and PhilipP. Power|2016|Organometallics|35|2759|doi:10.1021/acs.organomet.6b00519
CCDC 1505088: Experimental Crystal Structure Determination
2016
Related Article: Madison L. McCrea-Hendrick, ChristineA. Caputo, Jarno Linnera, Petra Vasko, CoryM. Weinstein, James C. Fettinger, Heikki M. Tuononen, and PhilipP. Power|2016|Organometallics|35|2759|doi:10.1021/acs.organomet.6b00519
CCDC 1505086: Experimental Crystal Structure Determination
2016
Related Article: Madison L. McCrea-Hendrick, ChristineA. Caputo, Jarno Linnera, Petra Vasko, CoryM. Weinstein, James C. Fettinger, Heikki M. Tuononen, and PhilipP. Power|2016|Organometallics|35|2759|doi:10.1021/acs.organomet.6b00519
CCDC 1008273: Experimental Crystal Structure Determination
2014
Related Article: Biswa Nath Ghosh, Filip Topić, Prasit Kumar Sahoo, Prasenjit Mal, Jarno Linnera, Elina Kalenius, Heikki M. Tuononen, Kari Rissanen|2015|Dalton Trans.|44|254|doi:10.1039/C4DT02728K
CCDC 1505085: Experimental Crystal Structure Determination
2016
Related Article: Madison L. McCrea-Hendrick, ChristineA. Caputo, Jarno Linnera, Petra Vasko, CoryM. Weinstein, James C. Fettinger, Heikki M. Tuononen, and PhilipP. Power|2016|Organometallics|35|2759|doi:10.1021/acs.organomet.6b00519
CCDC 941619: Experimental Crystal Structure Determination
2014
Related Article: Biswa Nath Ghosh, Filip Topić, Prasit Kumar Sahoo, Prasenjit Mal, Jarno Linnera, Elina Kalenius, Heikki M. Tuononen, Kari Rissanen|2015|Dalton Trans.|44|254|doi:10.1039/C4DT02728K
CCDC 1008276: Experimental Crystal Structure Determination
2014
Related Article: Biswa Nath Ghosh, Filip Topić, Prasit Kumar Sahoo, Prasenjit Mal, Jarno Linnera, Elina Kalenius, Heikki M. Tuononen, Kari Rissanen|2015|Dalton Trans.|44|254|doi:10.1039/C4DT02728K
CCDC 1505087: Experimental Crystal Structure Determination
2016
Related Article: Madison L. McCrea-Hendrick, ChristineA. Caputo, Jarno Linnera, Petra Vasko, CoryM. Weinstein, James C. Fettinger, Heikki M. Tuononen, and PhilipP. Power|2016|Organometallics|35|2759|doi:10.1021/acs.organomet.6b00519
CCDC 1008275: Experimental Crystal Structure Determination
2014
Related Article: Biswa Nath Ghosh, Filip Topić, Prasit Kumar Sahoo, Prasenjit Mal, Jarno Linnera, Elina Kalenius, Heikki M. Tuononen, Kari Rissanen|2015|Dalton Trans.|44|254|doi:10.1039/C4DT02728K
CCDC 1505084: Experimental Crystal Structure Determination
2016
Related Article: Madison L. McCrea-Hendrick, ChristineA. Caputo, Jarno Linnera, Petra Vasko, CoryM. Weinstein, James C. Fettinger, Heikki M. Tuononen, and PhilipP. Power|2016|Organometallics|35|2759|doi:10.1021/acs.organomet.6b00519
CCDC 1008274: Experimental Crystal Structure Determination
2014
Related Article: Biswa Nath Ghosh, Filip Topić, Prasit Kumar Sahoo, Prasenjit Mal, Jarno Linnera, Elina Kalenius, Heikki M. Tuononen, Kari Rissanen|2015|Dalton Trans.|44|254|doi:10.1039/C4DT02728K