0000000000370596
AUTHOR
S. Ordoñez
Emerging photocatalytic applications of graphitic carbon nitride
Graphitic carbon nitride assisted partial photocatalytic oxidation of the biomass platform molecule 5-hydroxymethyl-2-furfural (HMF) in aqueous medium was investigated. Different carbon nitride precursors were considered, being melamine the one yielding the most efficient photocatalyst The thermal exfoliation procedure of g-C3N4 gave rise to exfoliated samples with higher specific surface areas that also showed both an enhanced photocatalytic activity in conversion of HMF, and selectivity (ca. 42-45 %) towards FDC. The utilization of radical scavengers revealed that superoxide radicals were the main reactive species responsible for HMF oxidation to FDC. The use of natural solar light result…
Application of thermally exfoliated g-C3N4 for a green selective photocatalytic oxidation of 5-hydroxymethyl-2-furfural
Graphitic carbon nitride assisted partial photocatalytic oxidation of 5-hydroxymethyl-2-furfural (HMF) in aqueous medium was investigated. Different carbon nitride precursors were considered, being melamine the one yielding the most efficient photocatalyst. The obtained 30% selectivity of HMF oxidation towards 2,5-furandicarboxaldehyde (FDC) is higher than those reported up to now. A further thermal exfoliation of the g-C3N4 samples showed under artificial light irradiation both an enhanced photocatalytic activity in conversion of HMF, and selectivity (ca. 42-45 %) towards FDC. The performance of the catalysts increased when the experiments were carried out under real outdoor illumination, …
SARS-CoV-2 vaccination modelling for safe surgery to save lives: data from an international prospective cohort study
Abstract Background Preoperative SARS-CoV-2 vaccination could support safer elective surgery. Vaccine numbers are limited so this study aimed to inform their prioritization by modelling. Methods The primary outcome was the number needed to vaccinate (NNV) to prevent one COVID-19-related death in 1 year. NNVs were based on postoperative SARS-CoV-2 rates and mortality in an international cohort study (surgical patients), and community SARS-CoV-2 incidence and case fatality data (general population). NNV estimates were stratified by age (18–49, 50–69, 70 or more years) and type of surgery. Best- and worst-case scenarios were used to describe uncertainty. Results NNVs were more favourable in su…