Oxovanadium(IV) complexes with [ONNO]-chelating ligands as catalysts for ethylene homo- and copolymerization

2014

Oxovanadium(IV) complexes with (ONNO)-type tetradentate Schiff base ligands: salen, acacen, aceten, acetph (H2salen = N,N'-ethylenebis(salicylideneimine), H2aceten = N,N'-ethylenebis(2-hydroxyacetophenoneimine), H2acacen = N,N'-ethylenebis(acetylacetonimine), H 2 acetph = N ,N ' -phenylene-1,2-b is (2-hydroxyacetophenoneimine)), were the first time investi- gated in ethylene polymerization and ethylene/1-octene copo- lymerization processes. In general, all these complexes are moderately active precatalyst for ethylene polymerization up- on activation with EtAlCl2 and they give high molecular weight linear polyethylenes. Their activity in copolymeriza- tion was found relatively low. However,…