0000000000401122

AUTHOR

Gunay S. Mahmudova

showing 2 related works from this author

Aqua complex of iron(III) and 5-chloro-3-(2-(4,4-dimethyl-2,6- dioxocyclohexylidene) hydrazinyl)-2-hydroxybenzenesulfonate: Structure and catalytic a…

2013

Abstract A water-soluble iron(III) complex [Fe(H2O)3(L)]·5H2O (1) was prepared by reaction of iron(III) chloride with 5-chloro-3-(2-(4,4-dimethyl-2,6-dioxocyclohexylidene)hydrazinyl)-2-hydroxy-benzenesulfonic acid (H3L). The complex was characterized by IR, 1H NMR and ESI-MS spectroscopies, elemental and X-ray crystal structural analyses. The coordination environment of the central iron(III) is a distorted octahedron, three sites being occupied by L3− ligand, which chelates in O,N,O fashion, while three other sites are filled with the water molecules. The uncoordinated water molecules are held in the channels of the overall 3D supramolecular structure by the carbonyl and sulfonyl groups of …

Sulfonylchemistry.chemical_classificationNitroaldol reactionHalogen bondStereochemistryLigandHydrogen bondOrganic ChemistrySupramolecular chemistryMedicinal chemistryAnalytical ChemistryCatalysisInorganic Chemistrychemistry.chemical_compoundchemistryNitroethaneta116SpectroscopyJournal of molecular structure
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CCDC 919328: Experimental Crystal Structure Determination

2013

Related Article: Kamran T. Mahmudov, Maximilian N. Kopylovich, Matti Haukka, Gunay S. Mahmudova, Espandi F. Esmaeila, Famil M. Chyragov, Armando J.L. Pombeiro|2013|J.Mol.Struct.|1048|108|doi:10.1016/j.molstruc.2013.05.041

Triaqua-(5-chloro-2-oxy-3-((2-oxy-44-dimethyl-6-oxocyclohex-1-en-1-yl)diazenyl)benzenesulfonato)-iron(iii) pentahydrateSpace GroupCrystallographyCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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