0000000000409628
AUTHOR
László Bottyán
A common optical algorithm for the evaluation of specular spin polarized neutron and Mössbauer reflectivities
Using the general approach of Lax for multiple scattering of waves a 2x2 covariant expression for the reflectivity of polarized slow neutrons of a magnetic layer structure of arbitrary complexity is given including polarization effects of the external magnetic field. The present formalism is identical to the earlier published one for the (nuclear) resonant X-ray (Mossbauer) reflectivity and properly takes the effect of the external magnetic field of arbitrary direction on the neutron beam into account. The form of the reflectivity matrix allows for an efficient numerical calculation.
Switching Reciprocity On and Off in a Magneto-Optical X-Ray Scattering Experiment Using Nuclear Resonance ofα−Fe57Foils
Reciprocity is when the scattering amplitude of wave propagation satisfies a symmetry property, connecting a scattering process with an appropriate reversed one. We report on an experiment using nuclear resonance scattering of synchrotron radiation, which demonstrates that magneto-optical materials do not necessarily violate reciprocity. The setting enables us to switch easily between reciprocity and its violation. In the latter case, the exhibited reciprocity violation is orders of magnitude larger than achieved by previous wave scattering experiments.
57Co emission studies of cupric oxide
Results on the incorporation, valence and spin states of Fe(Co) in CuO (with reference to similar studies on high temperature superconductors) and coupling of the Fe(Co) moment to the Cu magnetism in CuO are presented. Freshly prepared57Co: CuO shows two quadrupole doublets D1 and D2 withQ.S. of 2.49 and 1.52,I.S. of 0.35 and 0.70 mm/s and relative abundance of 74% and 26%, respectively at room temperature, the abundance being dependent on time in a sample exposed to ambient conditions and reaching 38 to 62% fifteen months after preparation. Below,TN=2251K, a typical combined magnetic-quadrupole interaction pattern is observed with a single saturation magnetic hfs of 25.6 T, central shift o…
Coarsening of Antiferromagnetic Domains in Multilayers: The Key Role of Magnetocrystalline Anisotropy
The domain structure of an antiferromagnetic superlattice is studied. Synchrotron Mössbauer and polarized neutron reflectometric maps show micrometer-size primary domain formation as the external field decreases from saturation to remanence. A secondary domain state consisting mainly of at least 1 order of magnitude larger domains is created when a small field along the layer magnetizations induces a bulk-spin-flop transition. The domain-size distribution is reproducibly dependent on the magnetic prehistory. The condition for domain coarsening is shown to be the equilibrium of the external field energy with the anisotropy energy.
Comparative Mössbauer spectroscopic study of iron impurities in ZnSe
Abstract An anomalous spectral doublet attributed to Fe 2+ impurity pairs is observed in Mossbauer absorption spectra of 57 Fe 0.01 Zn 0.99 Se below room temperature. In Mossbauer emission experiments, ZnSe: 57 Co polycrystal and powder sources exhibit below 45 K the nucleogenic Fe 1+ valence state born as an after effect of the electron-capture decay of 57 Co. Above 8 K, the proportion of the nucleogenic Fe 1+ decreases under the effect of the thermally activated Fe 1+ →Fe 2+ relaxation. The activation energy is estimated to 0.004 eV. While nucleogenic Fe 1+ is absent in ZnSe: 57 Co single crystal spectra, increasing proportions are detected in samples with an enhanced specific surface. Th…
Coherent forward-scattering amplitude in transmission and grazing incidence Mössbauer spectroscopy
The theory of both transmission and grazing incidence M\"ossbauer spectroscopy is re-analyzed. Starting with the nuclear susceptibility tensor a common concise first order perturbation formulation is given by introducing the forward scattering amplitude into an anisotropic optical scheme. Formulae of Blume and Kistner as well as those of Andreeva are re-derived for the forward scattering and grazing incidence geometries, respectively. Limitations of several previously intuitively introduced approximations are pointed out. The grazing incidence integral propagation matrices are written in a form built up from 2x2 matrix exponentials which is particularly suitable for numerical calculations a…
Electron trapping centres and cross sections in LiNbO3studied by57Co Mössbauer emission spectroscopy
Fast electron trapping processes and aliovalent charge states following the 57Co(EC)57Fe decay are studied in undoped, 5.4 mol% Mg-doped and 0.1 mol% Fe-doped LiNbO3 in various thermochemical reduction (TCR) states. Static 57Co Mossbauer emission spectra of congruent Mg:LiNbO3 recorded at T = 4.2 K in external magnetic field of 4.6 T are presented. Trapping cross section ratios are derived for Fe3+Li, Nb5+Li and Mg2+Li. A method to determine trap concentrations for TCR states of LiNbO3 is outlined. The electron-capture distance of the traps is found to be 2.7±1.4 nm. As this is much smaller than the 6 keV Auger-electron penetration depth, it is concluded that the distribution of the alioval…
Stroboscopic detection of nuclear resonance in an arbitrary scattering channel
The theory of heterodyne/stroboscopic detection of nuclear resonance scattering is developed, starting from the total scattering matrix as a product of the matrix of the reference sample and the sample under study. This general approach holds for any dynamical scattering channel. The forward channel, which is discussed in detail in the literature, reveals the speciality that electronic scattering causes only an energy independent diminution of the intensity. For all other channels, complex resonance line shapes in the heterodyne/stroboscopic spectra - as a result of interference of electronic and nuclear scattering - is encountered. The grazing incidence case is evaluated and described in d…
Realizing total reciprocity violation in the phase for photon scattering
Scientific reports 7, 43114 (2017). doi:10.1038/srep43114
Synchrotron Mössbauer Reflectometry in Materials Science
57Fe nuclear resonant scattering experiments are reported on iron-containing thin films using 14.41 keV synchrotron radiation at angles of grazing incidence around and slightly above the critical angle of the electronic total reflection. In partially oxidised α–Fe films of 20 nm original thickness various oxide and oxihydroxide phases are identified at different depth. In a [Fe/FeSi]10multilayer grown on Zerodur®substrate the Fe—Fe interlayer coupling varies with the distance from the substrate. The antiferromagnetic order of the top layers of this multilayer can be suppressed by external magnetic field. These examples demonstrate the efficiency of synchrotron Mossbauer reflectometry (SMR),…