Correction to Impact of organoaluminum compounds on phenoxyimine ligands in coordinative olefin polymerization. A theoretical study

2013

Impact of Organoaluminum Compounds on Phenoxyimine Ligands in Coordinative Olefin Polymerization. A Theoretical Study

2013

The reduction of the phenoxyimine moiety in three individual species—namely free ligand, aluminum complex, and titanium complex—with aluminum alkyls and aluminum hydride has been studied by means of DFT. It was demonstrated that the free phenoxyimine ligand in an equimolar mixture with trimethylaluminum does not undergo reduction. Instead, experimentally observed formation of the six-membered cyclic aluminum–phenoxyimine complex, useful in the ring-opening polymerization of lactones, takes place as the kinetically and thermodynamically favored process. However, it is anticipated that a 2-fold excess of the aluminum compound, especially aluminum hydride, acting on the resulting cyclic comple…