Author: Thuy Minh Dau

0000000000423943

AUTHOR

Thuy Minh Dau

Ferrocenyl-functionalized tetranuclear gold(I) and gold(I)-copper(I) complexes based on tridentate phosphanes

Tetranuclear AuI–FeII dimetallic and AuI–CuI–FeII trimetallic complexes bearing ferrocenyl (Fc) groups have been assembled by using two triphosphane ligands, namely, (PPh2CH2)2PPh (dpmp) and (PPh2)3CH (tppm). The compositions and structural type of the clusters are dependent on the stereochemistry of the P donor ligands. The complexes [tppmAu3Cu(C2R)3]PF6 [R = Fc (1) and 4-C6H4-Fc (2)] adopt a trigonal pyramidal {Au3Cu} arrangement of the coordinating metal core, whereas for the compounds with the linear triphosphane [Au4(dpmp)2(C2R)2](PF6)2 [R = Fc (3) and 4-C6H4-Fc (4)], a planar rhomboidal {Au4} framework was found. Clusters 1–4 were characterized by NMR spectroscopy and ESI-MS measureme…

research product

CCDC 937899: Experimental Crystal Structure Determination

Related Article: Thuy Minh Dau, Julia R. Shakirova, Antonio Doménech, Janne Jänis, Matti Haukka, Elena V. Grachova, Tapani A. Pakkanen, Sergey P. Tunik, Igor O. Koshevoy|2013|Eur.J.Inorg.Chem.||4976|doi:10.1002/ejic.201300615

research product

CCDC 937897: Experimental Crystal Structure Determination

Related Article: Thuy Minh Dau, Julia R. Shakirova, Antonio Doménech, Janne Jänis, Matti Haukka, Elena V. Grachova, Tapani A. Pakkanen, Sergey P. Tunik, Igor O. Koshevoy|2013|Eur.J.Inorg.Chem.||4976|doi:10.1002/ejic.201300615

research product

CCDC 937898: Experimental Crystal Structure Determination

Related Article: Thuy Minh Dau, Julia R. Shakirova, Antonio Doménech, Janne Jänis, Matti Haukka, Elena V. Grachova, Tapani A. Pakkanen, Sergey P. Tunik, Igor O. Koshevoy|2013|Eur.J.Inorg.Chem.||4976|doi:10.1002/ejic.201300615

research product

PEPhysical Sciences and Engineering
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