0000000000425368

AUTHOR

Ahmed A.m. Sarhan

showing 2 related works from this author

A novel synthetic approach to pyran-2,4-dione scaffold production : microwave-assisted dimerization, cyclization, and expeditious regioselective conv…

2020

Here, we report a novel, green, simple, low-cost, and rapid methodology for the high-yield production of pyran-2,4-dione scaffolds under microwave irradiation. Regio- and stereoselective conversions of β-diketone systems into β-enaminones were achieved using 18 primary amines and four amino acid esters. Microwave-assisted further cyclization of 3-(β-substitutedvinyl)-6-phenyl-pyran-2,4-dione into 3-benzoyl-4,7-diphenyl-2H,5H-pyrano[4,3-b]pyran-2,5-dione via reaction with ethyl benzoyl acetate. peerReviewed

kemiallinen synteesimikroaallotmicrowavepyran-24-dioneintramolecular cyclizationorgaaniset yhdisteetβ-enaminones
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CCDC 2034810: Experimental Crystal Structure Determination

2020

Related Article: Ahmed A.M. Sarhan, Matti Haukka, Assem Barakat, Ahmed T.A. Boraei|2020|Tetrahedron Lett.|61|152660|doi:10.1016/j.tetlet.2020.152660

Space GroupCrystallography3-benzoyl-4-hydroxy-6-phenyl-2H-pyran-2-oneCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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