0000000000427285
AUTHOR
David López
<p><strong><em>Linaria semialata</em> and <em>L. amethystea </em>subsp.<em> aedoi</em>,<em> </em>two new taxa of <em>L.</em> sect. <em>Supinae </em>(<em>Plantaginaceae</em>) from Southeastern Iberian Peninsula</strong></p>
Two new taxa of the genus Linaria are described, illustrated and compared, through a morphometric analysis, to morphologically similar species from L. sect. Supinae: L. amethystea, L. diffusa, L. intricata, and L. orbensis. A Principal Component Analysis and Linear Discriminant Analysis were carried out in order to find out which morphological characters were the most important to discriminate these species. Morphometric analyses revealed that discrimination of species were more related to their particular morphological character combinations than to a private character. Two taxa are described as new to science, by providing a detailed description, illustrations, scanning-electron micrograp…
Synthesis, structural analysis, and thermal and spectroscopic studies of methylmalonate-containing zinc(II) complexes
The synthesis, crystal structure, thermal analysis and spectroscopic studies of five zinc(II) complexes of formulae [Zn(Memal)(H2O)]n (1) and [Zn2(L)(Memal)2(H2O)2]n (2-5) [H2Memal = methylmalonic acid, and L = 4,4′-bipyridine (4,4′-bpy) (2), 1,2-bis(4-pyridyl)ethylene (bpe) (3), 1,2-bis(4-pyridyl)ethane (bpa) (4) and 4,4′-azobispyridine (azpy) (5)] are presented here. The crystal structure of 1 is a three-dimensional arrangement of zinc(II) cations interconnected by methylmalonate groups adopting the μ3-κ2O:κO’:κO”:κO”’ coordination mode to afford a rare (10,3)-d utp-network. The structures of the compounds 2-5 are also three-dimensional and they consist of corrugated square layers of meth…