0000000000444939

AUTHOR

H. Werner

showing 5 related works from this author

Synthesis, Molecular Structure, and Reactivity of Rhodium(I) Complexes with Diazoalkanes and Related Substrates as Ligands

2003

A series of (diazoalkane)rhodium(I) compounds of the general composition trans-[RhCl(N2CRR‘)(PiPr3)2] with R = R‘ = Ph, p-C6H4Me, p-C6H4Cl and R = Ph, R‘ = p-C6H4Me, o-C6H4Me, CH3, CH2Ph, CF3 has been prepared from the dimer [RhCl(PiPr3)2]2 (1) and the diazoalkane. This preparative route has also been extended to complexes in which the N2C unit(s) of 1,4-C6H4{C(Ph)N2}2, 9-diazofluorene, 9,10-anthraquinone-9-diazide, and 3-methyl-1,4-naphthoquinone-1-diazide is (are) linked to a 14-electron [RhCl(PiPr3)2] fragment. While C(CO2Et)2N2 behaves as expected and affords upon treatment with 1 the complex trans-[RhCl{N2C(CO2Et)2}(PiPr3)2), CH(CO2Et)N2 reacts with the same starting material to give t…

ChemistryLigandStereochemistryDimerOrganic Chemistrychemistry.chemical_elementMedicinal chemistryRhodiumInorganic Chemistrychemistry.chemical_compoundMoleculeReactivity (chemistry)Physical and Theoretical ChemistryDerivative (chemistry)Organometallics
researchProduct

Chromatographie von Metallchelaten

1972

Die leichte Zuganglichkeit di-substituierter Dithiocarbamate erlaubt es, in einem breiteren Rahmen den Effekt unterschiedlicher Substitution auf die Trennung der Metall-dithiocarbamate (DTC) durch die Dunnschicht-Chromatographie zu untersuchen.

ChromatographyChemistryClinical BiochemistryGeneral Materials ScienceGeneral MedicineBiochemistryAnalytical ChemistryFresenius' Zeitschrift f�r Analytische Chemie
researchProduct

CCDC 207302: Experimental Crystal Structure Determination

2004

Related Article: H.Werner, N.Mahr, J.Wolf, A.Fries, M.Laubender, E.Bleuel, R.Garde, P.Lahuerta|2003|Organometallics|22|3566|doi:10.1021/om0302037

Space GroupCrystallographyCrystal SystemCrystal Structuretrans-Chloro-(1-(methoxycarbonyl)-2-(3-methylbutyl)ethanediketonediazo)-bis(tri-isopropylphosphine)-rhodium(i)Cell ParametersExperimental 3D Coordinates
researchProduct

CCDC 207300: Experimental Crystal Structure Determination

2004

Related Article: H.Werner, N.Mahr, J.Wolf, A.Fries, M.Laubender, E.Bleuel, R.Garde, P.Lahuerta|2003|Organometallics|22|3566|doi:10.1021/om0302037

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameterstrans-Chloro-(anthraquinonediazo)-bis(tri-isopropylphosphine)-rhodium(i)Experimental 3D Coordinates
researchProduct

CCDC 207301: Experimental Crystal Structure Determination

2004

Related Article: H.Werner, N.Mahr, J.Wolf, A.Fries, M.Laubender, E.Bleuel, R.Garde, P.Lahuerta|2003|Organometallics|22|3566|doi:10.1021/om0302037

Space GroupCrystallographyCrystal Systemtrans-Chloro-(tetrachlorocyclopentadienonediazo)-bis(tri-isopropylstibine)-rhodium(i)Crystal StructureCell ParametersExperimental 3D Coordinates
researchProduct