0000000000448215

AUTHOR

Marco Baron

0000-0001-6762-2240

showing 5 related works from this author

Structural and Luminescent Properties of Homoleptic Silver(I), Gold(I), and Palladium(II) Complexes with nNHC-tzNHC Heteroditopic Carbene Ligands

2019

Novel silver(I), gold(I), and palladium(II) complexes were synthesized with bidentate heteroditopic carbene ligands that combine an imidazol-2-ylidene (nNHC) with a 1,2,3-triazol-5-ylidene (tzNHC) connected by a propylene bridge. The silver(I) and gold(I) complexes were dinuclear species, [M-2(nNHC-tzNHC)(2)](PF6)(2) (M = Ag or Au), with the two bidentate ligands bridging the metal centers, whereas in the palladium(II) complex [Pd(nNHC-tzNHC)(2)]-(PF6)(2), the two ligands were chelated on the same metal center. Because of the presence of two different carbene units, isomers were observed for the gold(I) and palladium(II) complexes. The molecular structures of the head-to-tail isomer for gol…

Denticity010405 organic chemistryGeneral Chemical EngineeringINTEGRATION SCHEMEchemistry.chemical_elementGeneral Chemistry010402 general chemistry01 natural sciencesArticleREACTIVITY0104 chemical scienceslcsh:ChemistryELECTRONIC-PROPERTIESchemistry.chemical_compoundchemistrylcsh:QD1-999Polymer chemistrySTATISTICAL AVERAGEMETAL-COMPLEXESHomolepticLuminescenceCarbenePalladiumAPPROXIMATION
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CCDC 1873193: Experimental Crystal Structure Determination

2019

Related Article: Marco Monticelli, Marco Baron, Cristina Tubaro, Stéphane Bellemin-Laponnaz, Claudia Graiff, Gregorio Bottaro, Lidia Armelao, and Laura Orian|2019|ACS Omega|4|4192|doi:10.1021/acsomega.8b03668

Space GroupCrystallographyCrystal SystemCrystal Structurebis(3-methyl-1-phenyl-5-[3-(3-methylimidazol-2-ylidene-1-yl)propyl]-1H-123-triazol-3-ium)-palladium bis(hexafluorophosphate) acetonitrile solvateCell ParametersExperimental 3D Coordinates
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CCDC 1873190: Experimental Crystal Structure Determination

2019

Related Article: Marco Monticelli, Marco Baron, Cristina Tubaro, Stéphane Bellemin-Laponnaz, Claudia Graiff, Gregorio Bottaro, Lidia Armelao, and Laura Orian|2019|ACS Omega|4|4192|doi:10.1021/acsomega.8b03668

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu-3-benzyl-1-methyl-5-[3-(3-methylimidazol-2-ylidene-1-yl)propyl]-1H-123-triazol-3-ium)-di-gold bis(hexafluorophosphate)Experimental 3D Coordinates
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CCDC 1873191: Experimental Crystal Structure Determination

2019

Related Article: Marco Monticelli, Marco Baron, Cristina Tubaro, Stéphane Bellemin-Laponnaz, Claudia Graiff, Gregorio Bottaro, Lidia Armelao, and Laura Orian|2019|ACS Omega|4|4192|doi:10.1021/acsomega.8b03668

Space GroupCrystallographyCrystal SystemCrystal Structurebis(mu-3-phenyl-1-methyl-5-[3-(3-methylimidazol-2-ylidene-1-yl)propyl]-1H-123-triazol-3-ium)-di-gold bis(hexafluorophosphate) acetonitrile solvateCell ParametersExperimental 3D Coordinates
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CCDC 1873192: Experimental Crystal Structure Determination

2019

Related Article: Marco Monticelli, Marco Baron, Cristina Tubaro, Stéphane Bellemin-Laponnaz, Claudia Graiff, Gregorio Bottaro, Lidia Armelao, and Laura Orian|2019|ACS Omega|4|4192|doi:10.1021/acsomega.8b03668

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parametersbis(mu-3-phenyl-1-methyl-5-[3-(3-methylimidazol-2-ylidene-1-yl)propyl]-1H-123-triazol-3-ium)-di-gold bis(acetonitrile)-silver tris(hexafluorophosphate) diethyl ether solvateExperimental 3D Coordinates
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