0000000000462584

AUTHOR

Alessandro Pozzi

showing 2 related works from this author

Fast field cycling NMR relaxometry characterization of biochars obtained from an industrial thermochemical process

2012

Biochar has unique properties which make it a powerful tool to increase soil fertility and to contribute to the decrease of the amount of atmospheric carbon dioxide through the mechanisms of C sequestration in soils. Chemical and physical biochar characteristics depend upon the technique used for its production and the biomass nature. For this reason, biochar characterization is very important in order to address its use either for agricultural or environmental purposes. Three different biochars obtained from an industrial gasification process were selected in order to establish their chemical and physical peculiarities for a possible use in agronomical practices. They were obtained by char…

RelaxometryParamagnetic effectChemistryStratigraphySettore AGR/13 - Chimica AgrariaBiomassSoil scienceCarbon-13 NMRCarbon sequestrationBiocharFFC NMREnvironmental chemistryBiocharMagic angle spinningCPMAS 13C NMRCharCharringRelaxometryEarth-Surface Processes
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Nature of water-biochar interface interactions

2012

A poplar biochar obtained by an industrial gasification process was saturated with water and analyzed using fast field cycling (FFC) NMR relaxometry in a temperature range between 299 and 353 K. Results revealed that the longitudinal relaxation rate increased with the increment of the temperature. This behavior was consistent with that already observed for paramagnetic inorganic porous media for which two different relaxation mechanisms can be accounted for: outer- and inner-sphere mechanisms. The former is due to water diffusing from the closest approach distance to infinity, whereas the second is due to water interacting by nonconventional H-bonds to the porous surface of the solid materi…

Materials scienceRenewable Energy Sustainability and the EnvironmentEcologyDiffusionSettore AGR/13 - Chimica AgrariaForestryAtmospheric temperature rangebiochar char fast field cycling NMR gasification longitudinal relaxation time NMRD relaxometryChemical physicsSoil waterBiocharRelaxation (physics)CharPorosityPorous mediumWaste Management and DisposalAgronomy and Crop Science
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