0000000000465003

AUTHOR

Taras L. Panikorovskii

0000-0002-2323-1413

showing 6 related works from this author

Syntheses and Structures of a Series of Acyclic Diaminocarbene Palladium(II) Complexes Derived from 3,4-Diaryl-1H-pyrrol-2,5-diimines and Bisisocyani…

2018

Reactions of 3,4-diaryl-1H-pyrrol-2,5-diimines with various bisisocyanide palladium(II) complexes were studied. The coupling proceeds with one isocyanide ligand to accomplish the acyclic diaminocarbene complexes. The structure of generated diaminocarbene complexes depends on bulkiness of isocyanide ligand in the bisisocyanide complexes of palladium(II). The imino-group of 3,4-diaryl-1H-pyrrol-2,5-diimine reacts with one isocyanide ligand of cis-[PdCl2(CN–R)2] (R = i-Pr, Cy, t-Bu, Bn), and the nitrogen atom of the pyrrole ring is coordinated to the palladium center as the second isocyanide ligand remains intact. In the case of cis-[PdCl2(CN–R)2] (R = 2-acyloxyphenyl, 2-sulfonyloxyphenyl), on…

Coordination sphere010405 organic chemistryChemistryLigandIsocyanideOrganic Chemistrychemistry.chemical_elementMolecular spectroscopy010402 general chemistryRing (chemistry)01 natural sciences0104 chemical sciencesInorganic Chemistrychemistry.chemical_compoundPolymer chemistryPhysical and Theoretical ChemistryCyclic voltammetryPyrrolePalladiumOrganometallics
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Towards a revisitation of vesuvianite-group nomenclature: the crystal structure of Ti-rich vesuvianite from Alchuri, Shigar Valley

2016

Vesuvianite containing 5.85 wt% TiO2from an Alpine-cleft-type assemblage outcropped near Alchuri, Shigar Valley, Northern Areas, has been investigated by means of electron microprobe analyses, gas-chromatographic analysis of H2O, X-ray powder diffraction, single-crystal X-ray structure refinement,27Al NMR,57Fe Mössbauer spectroscopy, IR spectroscopy and optical measurements. Tetragonal unit-cell parameters are:a= 15.5326 (2),c= 11.8040 (2) Å, space groupP4/nnc. The structure was refined to finalR1= 0.031,wR2= 0.057 for 11247I> 2σ(I). A general crystal-chemical formula of studied sample can be written as follows (Z= 2):[8–9](Ca17.1Na0.9)[8]Ca1.0[5](Fe2+0.44Fe3+0.34Mg0.22)[6](Al3.59Mg0.41)…

Chromatography GasMagnetic Resonance SpectroscopySpectrophotometry InfraredCrystal chemistryIronInfrared spectroscopyMineralogyElectron microprobeCrystal structureengineering.materialCrystallography X-Ray010502 geochemistry & geophysics01 natural sciencesSpectroscopy MossbauerTetragonal crystal systemX-Ray Diffraction0502 economics and businessMössbauer spectroscopyMaterials ChemistryPakistanVesuvianite0105 earth and related environmental sciencesTitaniumMineralsChemistry05 social sciencesMetals and AlloysAtomic and Molecular Physics and OpticsElectronic Optical and Magnetic MaterialsCrystallographyengineering050211 marketingPowdersPowder diffractionActa Crystallographica Section B Structural Science, Crystal Engineering and Materials
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CCDC 1817631: Experimental Crystal Structure Determination

2018

Related Article: Dina V. Boyarskaya, Evgeny Bulatov, Irina A. Boyarskaya, Tatiana G. Chulkova, Valentin A. Rassadin, Elena G. Tolstopjatova, Ilya E. Kolesnikov, Margarita S. Avdontceva, Taras L. Panikorovskii, Vitalii V. Suslonov, Matti Haukka|2018|Organometallics|38|300|doi:10.1021/acs.organomet.8b00725

Space GroupCrystallography(mu-chloro)-(mu-2-azanidylidene-34-bis(4-methoxyphenyl)-5-((((propan-2-yl)imino)methyl)imino)-25-dihydropyrrolyl)-(2-iminio-34-bis(4-methoxyphenyl)-5-((((propan-2-yl)imino)methyl)imino)-25-dihydropyrrolyl)-chloro-di-palladiumCrystal SystemCrystal StructureCell ParametersExperimental 3D Coordinates
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CCDC 1818370: Experimental Crystal Structure Determination

2018

Related Article: Dina V. Boyarskaya, Evgeny Bulatov, Irina A. Boyarskaya, Tatiana G. Chulkova, Valentin A. Rassadin, Elena G. Tolstopjatova, Ilya E. Kolesnikov, Margarita S. Avdontceva, Taras L. Panikorovskii, Vitalii V. Suslonov, Matti Haukka|2018|Organometallics|38|300|doi:10.1021/acs.organomet.8b00725

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(2-{[(t-butylimino)methanidyl]imino}-5-iminio-34-diphenyl-25-dihydropyrrol-1-yl)-chloro-(2-isocyano-2-methylpropane)-palladium chloride dichloromethane solvateExperimental 3D Coordinates
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CCDC 1817212: Experimental Crystal Structure Determination

2018

Related Article: Dina V. Boyarskaya, Evgeny Bulatov, Irina A. Boyarskaya, Tatiana G. Chulkova, Valentin A. Rassadin, Elena G. Tolstopjatova, Ilya E. Kolesnikov, Margarita S. Avdontceva, Taras L. Panikorovskii, Vitalii V. Suslonov, Matti Haukka|2018|Organometallics|38|300|doi:10.1021/acs.organomet.8b00725

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(mu-cyano)-({[5-amino-34-bis(4-methylphenyl)-2H-pyrrol-2-ylidene]amino}(t-butylamino)methylidene)-({[5-amino-34-bis(4-methylphenyl)pyrrol-1-id-2-yl]amino}(t-butylamino)methylidene)-dichloro-di-palladium(ii) dichloromethane solvate monohydrateExperimental 3D Coordinates
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CCDC 1822187: Experimental Crystal Structure Determination

2018

Related Article: Dina V. Boyarskaya, Evgeny Bulatov, Irina A. Boyarskaya, Tatiana G. Chulkova, Valentin A. Rassadin, Elena G. Tolstopjatova, Ilya E. Kolesnikov, Margarita S. Avdontceva, Taras L. Panikorovskii, Vitalii V. Suslonov, Matti Haukka|2018|Organometallics|38|300|doi:10.1021/acs.organomet.8b00725

Space GroupCrystallographyCrystal SystemCrystal StructureCell Parameters(2-iminio-5-{[({5-methyl-2-[(4-methylbenzene-1-sulfonyl)oxy]phenyl}imino)methanidyl]imino}-34-diphenyl-25-dihydropyrrol-1-yl)-bis(chloro)-palladium acetonitrile solvateExperimental 3D Coordinates
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