Azido and thiocyanato bridged dinuclear Ni(II) complexes involving 8-aminoquinoline based Schiff base as blocking ligands: Crystal structures, ferromagnetic properties and magneto-structural correlations
Abstract The use of two 8-aminoquinoline-based tridentate N3-donor rigid Schiff base ligands (L1 and L2) with Ni(II) in the presence of the pseudohalides, NaN3 and NaSCN results in the crystallization of the two novel Ni(II) dimers: [Ni2(L1)2(µ1,1′-N3)2(N3)2] (1) and [Ni2(L2)2(µ1,3-NCS)2(NCS)2] (2). Both complexes are centrosymmetric Ni(II) dimers where the Schiff base ligands coordinate the octahedral Ni(II) centres in a mer configuration with one terminal and two bridging pseudohalide ligands in the remaining positions. Complex 1 shows Ni(II) ions connected by a double µ1,1′-N3− bridge whereas in complex 2 the Ni(II) ions are connected by a double µ1,3-NCS− bridge. The magnetic properties…
Multifunctional Ni(II)-Based Metamagnetic Coordination Polymers for Electronic Device Fabrication
The combination of two 8-aminoquinoline-based Schiff base ligands (L1 and L2) with SCN– and Ni(II) has led to the synthesis of two new one-dimensional thiocyanato-bridged coordination polymers: [Ni...
CCDC 1936484: Experimental Crystal Structure Determination
Related Article: Pravat Ghorai, Arka Dey, Paula Brandão, Samia Benmansour, Carlos J. Gómez García, Partha Pratim Ray, Amrita Saha|2020|Inorg.Chem.|59|8749|doi:10.1021/acs.inorgchem.0c00389
CCDC 1936483: Experimental Crystal Structure Determination
Related Article: Pravat Ghorai, Arka Dey, Paula Brandão, Samia Benmansour, Carlos J. Gómez García, Partha Pratim Ray, Amrita Saha|2020|Inorg.Chem.|59|8749|doi:10.1021/acs.inorgchem.0c00389
CCDC 1918388: Experimental Crystal Structure Determination
Related Article: Pravat Ghorai, Paula Brandão, Samia Benmansour, Carlos J. Gómez García, Amrita Saha|2020|Polyhedron|188|114708|doi:10.1016/j.poly.2020.114708
CCDC 1918387: Experimental Crystal Structure Determination
Related Article: Pravat Ghorai, Paula Brandão, Samia Benmansour, Carlos J. Gómez García, Amrita Saha|2020|Polyhedron|188|114708|doi:10.1016/j.poly.2020.114708